研究目的
Enhancing the sensitivity of a cantilever-enhanced photo-acoustic spectroscopic sensor by an optical build-up cavity.
研究成果
The CE-CEPAS technique achieves an unprecedented normalised noise equivalent absorption (NNEA) value of 1.75×10-12 W cm-1 Hz -1/2, resulting in 75 ppt noise equivalent concentration for C2H2 with a 10 s integration time in the 1530 nm wavelength range. Compared to standard CEPAS, the detection limit is better by a factor of 100, corresponding to the power build-up factor (BUF) of the cavity.
研究不足
The selection of wavelengths and tunability of high power narrow linewidth lasers is limited, and they are rarely suitable for field deployable analysers.
1:Experimental Design and Method Selection:
The setup consists of a
2:5 mW DFB laser coupled into a linear optical cavity that accommodates the CEPAS sensor. The cavity has a finesse of ~200, optimized for the linewidth of the DFB laser. The photo-acoustic signal is obtained by wavelength modulation with second harmonic detection. Sample Selection and Data Sources:
The sensor response is calibrated, and an Allan deviation analysis is performed for both CE-CEPAS and CEPAS.
3:List of Experimental Equipment and Materials:
A
4:5 mW DFB laser, a linear optical cavity with a finesse of ~200, and a CEPAS sensor. Experimental Procedures and Operational Workflow:
The wavelength modulation at 30 Hz involves a continuous lock of the laser frequency to the cavity by the dither-and-lock method and dithering one of the cavity mirrors to change the resonance frequency of the cavity.
5:Data Analysis Methods:
The difference between CE-CEPAS and CEPAS gives the BUF of 100, which agrees with the cavity design.
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