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Dielectric, ferroelectric, and photovoltaic properties of La-doped Bi(Ni2/3Ta1/3)O3–PbTiO3 ceramics

DOI:10.1016/j.jallcom.2019.152191 期刊:Journal of Alloys and Compounds 出版年份:2019 更新时间:2025-09-11 14:15:04
摘要: Bi(Ni2/3Ta1/3)O3-PbTiO3 ceramics doped with different La contents were prepared using the conventional solid-state reaction route. The electric properties of La-doped Bi(Ni2/3Ta1/3)O3-PbTiO3 ceramics were compared with those of non-La ceramics. As the incorporated La content increased, the Curie temperature TC decreased linearly, whereas the dielectric constant ε'RT at room temperature increased. Although the remnant polarization Pr decreased, the bipolar strain S (%) increased as the La content increased, owing to phase transition from the ferroelectric phase to the paraelectric phase. The maximum bipolar strain S (0.42%) was observed in the Bi0.7La0.3(Ni2/3Ta1/3)O3-PbTiO3 ceramics. When the La content reached 50%, the ferroelectric performance deteriorated. After La was doped into the Bi(Ni2/3Ta1/3)O3-PbTiO3 ceramics, the photovoltages were markedly improved. The photovoltage (27 V) reached its maximum with 15% La content but was reduced to 0 V with 50% La doping content owing to a decline in ferroelectricity. The speed of the photovoltaic response to the incident light for this system was about 0.5 ms. Therefore, the strain and the photovoltaic properties of the La-doped Bi(Ni2/3Ta1/3)O3-PbTiO3 ceramics were markedly improved relative to those of undoped ceramics.
作者: Dongfang Pang,Tongxiang Liang,Yiqun Deng,Honghui Jiang,Xinmei Hou,Xifa Long
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Investigating the dielectric, ferroelectric, and photovoltaic properties of La-doped Bi(Ni2/3Ta1/3)O3–PbTiO3 ceramics to understand the effects of La doping on these properties.

La doping transforms the structure of Bi(Ni2/3Ta1/3)O3-PbTiO3 ceramics from a tetragonal ferroelectric phase to a cubic paraelectric phase, affecting their dielectric, ferroelectric, and photovoltaic properties. The maximum photovoltage was achieved with 15% La doping, but ferroelectric performance deteriorated at 50% La doping. The photovoltaic response was fast, making these ceramics potential alternatives for conventional photovoltaic materials.

The study is limited to the effects of La doping on the properties of Bi(Ni2/3Ta1/3)O3–PbTiO3 ceramics and does not explore other dopants or materials.

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