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Facile green and one-pot synthesis of purple perilla derived carbon quantum dot as a fluorescent sensor for silver ion

DOI:10.1016/j.talanta.2019.03.095 期刊:Talanta 出版年份:2019 更新时间:2025-09-11 14:15:04
摘要: Coalbed methane (CBM) reservoir pore structure is extremely complex and heterogeneous. With the fractal theory, the geometric and structural characteristics of the pore structure could be quanti?ed. However, few studies have aimed to understand the fractal features of compositional-based macrolithotypes (bright, semi-bright, semi-dull, and dull coals). In this work, samples from the Hancheng area, in the southeastern Ordos Basin, China, were collected to investigate the fractal features of pore structures for macrolithotypes and calculate fractal dimensions (Da1 and Da2 for adsorption pores; Ds1 and Ds2 for seepage pores) based on low temperature N2 adsorption and mercury intrusion data, respectively. Meanwhile, the impact of the fractal dimensions on the gas adsorption capacity and the seepage ability were discussed. The results demonstrate that when bright coal turns into dull coal, the vitrinite content, helium permeability, and gas adsorption capacity gradually decrease, while the coal density, mineral content, and ash yield increase. Since the Da1 and Ds1 either deviate from the natural fractal dimension (2 < D < 3) or have a poor correlation with macrolithotypes, Da2 and Ds2 are regarded as the adsorption and seepage pore fractal dimensions, respectively. Of all the coal macrolithotypes, bright coal has the smallest BET speci?c surface area and micropore proportion, which results in the smallest fractal dimension Da2, while for the dull coal, this is just the contrary; due to the higher mineral content, a higher Da2 of the dull coal indicates a more complicated adsorption pore structure, and the coal with a larger Langmuir volume has a smaller Da2. For the seepage pores, when the bright coal turns into dull coal, the macropore proportion gradually decreases, but the pore proportion tends toward equilibrium, and the mercury withdrawal e?ciency increases; the dull coal has a larger Ds2, indicating a more complex seepage pore structure than that in the bright coal. Due to the decreasing macropore proportion and mineral ?lling, Ds2 demonstrates an obvious negative correlation with the helium permeability and macropore proportion.
作者: Junlong Zhao,Dazhen Tang,Yong Qin,Hao Xu
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To investigate the fractal features of pore structures for macrolithotypes and calculate fractal dimensions based on low temperature N2 adsorption and mercury intrusion data, and discuss the impact of the fractal dimensions on the gas adsorption capacity and the seepage ability.

The study concludes that Da2 and Ds2 are the appropriate fractal dimensions for adsorption and seepage pores, respectively. Bright coal has the smallest fractal dimension Da2, while dull coal has the highest due to higher mineral content. The fractal dimension Ds2 shows a negative correlation with helium permeability and macropore proportion.

The study focuses on coal macrolithotypes from the Hancheng area, which may not be representative of all coal types. The fractal dimensions Da1 and Ds1 either deviate from the natural fractal dimension or have a poor correlation with macrolithotypes, limiting their applicability.

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