研究目的
Investigating the growth, optical, thermal, mechanical, laser damage threshold, and electrical polarizability of Cadmium Chloride doped L-Alanine (LACC) single crystal for optoelectronic applications.
研究成果
The LACC crystal exhibits high transmission in the visible region, thermal stability up to 233°C, and a melting point of 298°C. It belongs to the soft material category with a high laser damage threshold and significant nonlinear optical properties, making it suitable for optoelectronic device fabrication.
研究不足
The study is limited to the characterization of LACC crystals under specific conditions and does not explore the effects of varying dopant concentrations or alternative growth methods.
1:Experimental Design and Method Selection:
The LACC crystal was grown by slow evaporation technique using de-ionized water as solvent. Single crystal x-ray diffraction, FT-IR, UV–Vis-NIR, TG-DTA, microhardness, and Z-scan techniques were employed for characterization.
2:Sample Selection and Data Sources:
L-alanine (LOBA) and cadmium chloride (MERCK) in a 1:
3:1 molar ratio were used. List of Experimental Equipment and Materials:
BRUKER APEX 2 for x-ray diffraction, Perkin Elmer LAMDA 950 for UV–Vis-NIR, NETZSCH STA 449 F3 Jupiter for TG-DTA, Shimadzu microhardness analyzer, and Nd: YAG laser for Z-scan.
4:Experimental Procedures and Operational Workflow:
The solution was stirred for 4 h, filtered, and allowed to evaporate slowly. Crystals were harvested after 37 days.
5:Data Analysis Methods:
The optical band gap was calculated using Tauc’s plot, and nonlinear parameters were determined using Z-scan technique.
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