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Chemical analysis of a lunar meteorite by laser ablation mass spectrometry

DOI:10.1016/j.pss.2019.104816 期刊:Planetary and Space Science 出版年份:2019 更新时间:2025-09-12 10:27:22
摘要: The lunar meteorite Sayh al Uhaymir 169, that contains KREEP rich material, was investigated with our miniature laser ablation time-of-flight mass spectrometer to simulate the expected performance of in-situ measurements on the surface of a planetary body. The abundances of the major elements on the KREEP part of the rock were measured and plotted on a two-dimensional surface map to identify different mineral phases in the sample. The element distribution maps reveal the grain boundaries and allow identification of individual minerals and their major and trace element compositions. In the second measurement campaign the instrument was coupled with a HV pulser to increase sensitivity of the measurements. It could be shown that the detection sensitivity for heavy trace elements can be significantly improved while removing light elements from the analyzed ion beam. This study provides also measurements of U, Th and Pb elements present inside a single zircon grain. With the abundances of U and Pb in the zircon grain a preliminary age estimation of the zircon could be made and was found to be in reasonable agreement with ages reported in literature. Moreover, from the Ti concentration in the zircon grain a crystallization temperature was derived. Thus, by employing such an instrument on a planetary surface, scientific useful in-situ measurements on the element composition, the mineralogy, petrology and dating of surface samples can be accomplished.
作者: Samira Frey,Reto Wiesendanger,Marek Tulej,Maike Neuland,Andreas Riedo,Valentine Grimaudo,Pavel Moreno-García,Alena Cede?o López,Miklós Mohos,Beda Hofmann,Klaus Mezger,Peter Broekmann,Peter Wurz
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Investigating the chemical composition and mineralogy of the lunar meteorite Sayh al Uhaymir 169 using laser ablation mass spectrometry to simulate in-situ planetary surface measurements.

The study demonstrated the capability of a miniature laser ablation mass spectrometer for in-situ chemical analysis of planetary materials, including major and trace element composition, mineral identification, and age estimation. The technique shows promise for future planetary exploration missions.

The study's limitations include the potential for terrestrial contamination affecting light element abundances and the need for more measurements to improve the statistical quality of age determinations. The exact composition of the parent magma from which zircon crystallized is not known, introducing uncertainty in temperature estimates.

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