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The versatility of passivating carrier‐selective silicon thin films for diverse high‐efficiency screen‐printed heterojunction‐based solar cells

DOI:10.1002/pip.3227 期刊:Progress in Photovoltaics: Research and Applications 出版年份:2019 更新时间:2025-09-12 10:27:22
摘要: Providing state‐of‐the‐art surface passivation and the required carrier selectivity for both contacts, hydrogenated amorphous silicon thin films are the key components of silicon heterojunction (SHJ) solar cells. After intensive optimization of these layers for standard front and back contacted (FBC) n‐type cells, high surface passivation levels were achieved on cell precursors, demonstrated by minority carrier lifetimes exceeding 18 ms on float‐zone (FZ) and 11 ms on Czochralski (Cz) c‐Si wafers. The application of these very same layers on cheaper and commercially available Cz p‐type wafers resulted in similar passivation quality, with lifetimes above 10 ms as well. Large‐area industrial bifacial FBC SHJ cells processed on wafers taken along the full length of a high‐resistivity Cz p‐type ingot showed efficiencies in the 22.5% to 23% range, significantly higher than previously reported results on such substrates and on par with their n‐type counterparts. Best efficiencies on large‐area monofacial devices (>220 cm2) are 23.6% on Cz p‐type and 24.4% on Cz n‐type, similar to certified results obtained on lab‐scale cells (4 cm2), 23.76% on FZ p‐type and 24.21% on FZ n‐type. Notably, no specific adaptation of the reference n‐type cell process was necessary to achieve these results on p‐type material. Additionally, a 25% certified efficiency has been obtained on medium‐sized (25 cm2) interdigitated back‐contacted SHJ cells, featuring the same passivation layers developed for FBC devices. These results illustrate the versatility of the SHJ technology for various high‐efficiency screen‐printed solar cell configurations and show possible ways to improve its competitiveness on the global photovoltaic market.
作者: Antoine Descoeudres,J?rg Horzel,Bertrand Paviet‐Salomon,Laurie‐Lou Senaud,Gabriel Christmann,Jonas Geissbühler,Patrick Wyss,Nicolas Badel,Jan‐Willem Schüttauf,Jun Zhao,Christophe Allebé,Antonin Faes,Sylvain Nicolay,Christophe Ballif,Matthieu Despeisse
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Investigating the versatility of passivating carrier‐selective silicon thin films for diverse high‐efficiency screen‐printed heterojunction‐based solar cells.

The SHJ technology demonstrates high‐efficiency potential with a simple fabrication process applicable at the industrial scale. The study shows that processes optimized for n‐type substrates can be directly applied to p‐type ones, achieving high performance levels (>23.5% on large‐area cells). This opens the door for the use of Cz p‐type wafers in mass production, improving the technology's competitiveness. Additionally, the developed intrinsic passivating layers are effective for advanced IBC cells, with certified efficiencies up to 25%.

The study acknowledges potential light‐induced degradation effects in p‐type SHJ cells and the need for further optimization to match n‐type cell efficiencies fully.

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