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Sono-photodeposition of Ag over sono-fabricated mesoporous Bi2Sn2O7-two dimensional carbon nitride: Type-II plasmonic nano-heterojunction with simulated sunlight-driven elimination of drug

DOI:10.1016/j.cej.2019.123418 期刊:Chemical Engineering Journal 出版年份:2019 更新时间:2025-09-12 10:27:22
摘要: The mesoporous Ag/Bi2Sn2O7-C3N4 plasmonic nanophotocatalyst, which synthesized by the hybridization method of sono-dispersion and heat-treatment following with the sono-photodeposition, was applied as an efficient solar-light-driven photocatalyst for degradation of Tetracycline (TC) antibiotic. Also, the Bi2Sn2O7, g-C3N4, Bi2Sn2O7-C3N4, Ag/Bi2Sn2O7 and Ag/C3N4 nanophotocatalysts were synthesized to compare. The characterizations of samples were conducted using XRD, morphology analyses such as FESEM, TEM and AFM, EDX and dot mapping, BET-BJH, FTIR, DRS and pHpzc. The results of morphology analyses showed that about 75.2% of nanoparticles are at the range of 10-20 nm and the minimum and maximum particle sizes were 6.9 nm and 42.2 nm respectively. Moreover, the cubic Ag particles size was about 25.7 nm. Besides, the results of the UV-vis diffuse reflectance spectroscopy analysis illustrated the promotion of the absorption edge of Ag/Bi2Sn2O7-C3N4 (at about 521nm) following with the decrement of band gap (2.38 eV). The photocatalytic activity of Ag/Bi2Sn2O7-C3N4 was obtained higher than other samples (89.1%) due to Bi2Sn2O7-C3N4 type-II heterojunction, porous structure with high specific surface area (66 m2/g) owing to the usage of ultrasonic energy and surface plasmon resonance created using the Ag particle. Moreover, experiments were carried out to investigate the effect of various parameters such as the photocatalyst dosage, initial concentration and pH of TC solution in removing the contaminate molecule from aqueous solution under the light illumination, which was simulated as sunlight, in the presence of photocatalyst and the possible elimination mechanism was proposed for pollutant removal.
作者: Shirin Heidari,Mohammad Haghighi,Maryam Shabani
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The principal aims of this study were: (1) fabrication of the mesoporous Ag/Bi2Sn2O7-C3N4 plasmonic nanophotocatalyst with type-II heterojunction nanostructure using the hybridation rout of sono-dispersion and heat-treatment; (2) the utilization of the ultrasound energy owing to the creation of the suitable distribution and nucleation; (3) the effect of Ag on the optical, physico-chemical features; (4) the evaluation of antibiotic tetracycline degradation by the Ag/Bi2Sn2O7-C3N4 plasmonic nanophotocatalyst under the light illumination, which was simulated as sunlight.

Mesoporous Ag/Bi2Sn2O7-C3N4 nanocomposite demonstrated significant photocatalytic efficiency (89.1%) for TC degradation under simulated solar light. The excellent photocatalytic efficiency can be attributed to several factors including the creation of type-II heterojunction between BSO and BCN semiconductors, loading Ag particles over the BSO-BCN composite and creating surface plasmonic resonance, and the use of ultrasound during the synthesis.

The study does not mention any specific limitations.

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