研究目的
Investigating the effect of incorporating (CuO/PbI2/CH3NH3I/ZnO) on porous silicon (p-Psi) for the fabrication of hybrid Perovskite solar cells.
研究成果
The research successfully fabricated a perovskite solar cell using (CuO, ZnO) nanoparticles and porous silicon, achieving a power conversion efficiency of 8.21%. The nanostructured materials used as electrodes improved the photovoltaic properties of the solar cell.
研究不足
The study does not discuss the scalability of the fabrication process or the long-term stability of the solar cells under operational conditions.
1:Experimental Design and Method Selection:
The study used the drop casting technique at 70°C to incorporate (CuO/PbI2/CH3NH3I/ZnO) on porous silicon (p-Psi). Structural, optical, and morphological properties were characterized using X-ray diffraction, UV–Vis spectrophotometer, scanning electron microscopy, and atomic force microscopy.
2:Sample Selection and Data Sources:
Porous silicon was prepared using a p-type silicon wafer with an electrolytic Teflon cell containing hydrofluoric acid and ethanol. CuO and ZnO nanoparticles were synthesized by chemical precipitation methods.
3:List of Experimental Equipment and Materials:
Equipment included an electrode instrument for manufacturing porous silicon, thermal evaporation technique for aluminium deposition, and UV–VIS double beam UVD-3500 for optical absorption measurements. Materials included silicon wafer, hydrofluoric acid, ethanol, copper nitrate, sodium hydroxide, zinc sulphate heptahydrate, and N, N Dimethyl Formamide (DMF).
4:Experimental Procedures and Operational Workflow:
The process involved the preparation of porous silicon, synthesis of CuO and ZnO nanoparticles, preparation of MAPbI3-film, and fabrication of the PV device using drop-casting and sintering.
5:Data Analysis Methods:
The crystalline size was calculated using the Debye-Scherrer formula. Optical properties were analyzed to estimate the band gap, and photovoltaic properties were measured to calculate power conversion efficiency and fill factor.
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