研究目的
To further improve the performance of polymer solar cells by designing parallel-connected tandem cells using a highly efficient donor polymer, PTB7-Th, combined with acceptor fullerene PC71BM as the back sub-cell.
研究成果
The simulation results demonstrate that PTB7-Th based tandem solar cells have great potential for use in high-performance applications, with a predicted device efficiency up to ~11%, which is ~15% higher than that of a single cell of PTB7-Th.
研究不足
The study is based on theoretical modeling and simulation, and the actual device performance may vary due to potential loss in charge recombination, transport, and collection.
1:Experimental Design and Method Selection:
Optical modeling based on the transfer matrix method (TMM) was performed to calculate the interference of reflected and transmitted light waves at each interface in the stack based on the wavelength-dependent complex index of refraction (n + ik) of each material.
2:Sample Selection and Data Sources:
PTB7-Th:PC71BM BHJ film was used as the active layer of back sub-cells in all devices.
3:List of Experimental Equipment and Materials:
Ultrathin Ag film was used as the semitransparent metal interlayer.
4:Experimental Procedures and Operational Workflow:
The effect of active layer thickness, different device structure, and ultrathin Ag film on the optical absorption and thus current density were analyzed.
5:Data Analysis Methods:
The theoretical lossless photocurrent of each simulated condition was calculated by integrating with the light spectrum of the AM 1.5 global solar spectrum and assuming a unity photon-to-electron conversion.
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