摘要： Two blue ?uorescent dendrimers named PVAC2 and PVACA have been newly synthesized and investigated, where the carbazole/diphenylamine hybrid dendron is adopted instead of oligocarbazole. Compared with the reference dendrimer PVCt3, the emission maxima of PVAC2 and PVACA are found to be red-shifted accompanied by a slight reduction of the photoluminescence quantum yield in ?lms. Most importantly, the highest occupied molecular orbital level is elevated from ?5.35 eV of PVCt3 to ?5.20 eV of PVAC2 and ?4.95 eV of PVACA. Because of the favored hole injection, the turn-on voltage is accordingly decreased from 3.6 to 3.2 and 2.6 V. The value of PVACA is even lower than the theoretical limit of 2.78 V. In addition, PVAC2 exhibited the best nondoped device performance, showing a nearly doubled power e?ciency of 4.80 lm/W relative to PVCt3 (2.37 lm/W). The results clearly indicate that dendron engineering is also a promising strategy to develop solution-processible blue ?uorescent dendrimers capable of being used for power-e?cient organic light-emitting diodes.