研究目的
Investigating the feasibility of fabricating phosphorescent top-emitting OLEDs using a solution process with a simple OLED structure and replacing indium tin oxide electrode by a low-cost reflective aluminum electrode.
研究成果
The study demonstrates the feasibility of fabricating phosphorescent top-emitting OLEDs using a solution process with a simple structure and a low-cost reflective aluminum electrode. Optical properties are relatively well-optimized, showing a low emission shift and angle dependency, indicating control over microcavity effects.
研究不足
The current efficiency of top-emitting OLEDs is lower than that of bottom-emitting OLEDs. The study demonstrates feasibility but indicates room for improvement in efficiency and performance.
1:Experimental Design and Method Selection:
The study compares the performances of top-emitting and bottom-emitting OLEDs based on the same emissive material (iridium complex).
2:Sample Selection and Data Sources:
OLEDs are built on 25 by 25 mm2 glass substrates, covered by an indium tin oxide (ITO) layer for BOLEDs and by a 140 nm thick aluminum layer for TOLEDs.
3:List of Experimental Equipment and Materials:
Includes zinc oxide nanoparticles, polyethylenimine-ethoxylated (PEIE), 1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene (TPBi), iridium complexes (Ir(mppy)3 and Ir(ppy)3), poly(N-vinylcarbazole) (PVK), and others.
4:Experimental Procedures and Operational Workflow:
Describes the fabrication process, including cleaning, spin-coating, annealing, and thermal evaporation steps.
5:Data Analysis Methods:
Electroluminescence spectrum and current density-voltage-luminance (JVL) characteristics are measured using specific equipment.
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tris[2-(phenylpyridinato-C2, N]iridium(III)
Ir(ppy)3
Sigma-Aldrich
Used as an emitter in the OLED.
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Andor SR-500i spectrometer
SR-500i
Andor
Used for measuring the electroluminescence spectrum.
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Keithley 2400
2400
Keithley
Used as a Source Measure Unit (SMU) for recording current density-voltage-luminance (JVL) characteristics.
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zinc oxide nanoparticles
Genes’ink
Used as a layer in the OLED fabrication process.
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polyethylenimine-ethoxylated
Sigma-Aldrich
Used as electron injection material.
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1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene
Lumtec
Used as hole blocking material.
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tris[2-(p-tolyl)pyridine]iridium(III)
Ir(mppy)3
Lumtec
Used as an emitter in the OLED.
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poly(N-vinylcarbazole)
PVK
Used as a host for iridium complexes.
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