研究目的
The aim of this study is to develop and optimize a low temperature processable TiO2 formulation suitable for both screen printing and spray coating.
研究成果
In summary, different formulations of a low temperature processed TiO2 film have been developed and investigated in this study using both screen printing and spray coating techniques. The high temperature processed DSSCs were successfully achieved with a PCE of 7.41 % based on the formulated TiO2 paste/ink via screen printing and 6.65 % via spray coating, at the same time, low temperature processed DSSCs has been achieved with a PCE of 4.3 % via screen printing and 2.58 % via spray coating. Both screen printed and spray coated DSSCs on glass substrates have been demonstrated using a low temperature annealing processing. This optimized formulation is suitable for mass production and can provide low cost processing photo anode materials suitable for a wide range of potential flexible substrates, such as flexible plastics and wearable textiles.
研究不足
The high processing temperatures limit their application on, for example, textile substrates.
1:Experimental Design and Method Selection:
The study investigates low temperature (150 oC) processed TiO2 formulations, with and without a binder system, in two different solvents and the use of a nano particle stabiliser. The study applies to and benefits both screen printing and spray coating techniques.
2:Sample Selection and Data Sources:
Pre-coated FTO coated glass substrates were used for the photo anode and cathode. Aeroxide TiO2 P25 nanoparticles with a primary particle size of 21 nm was used.
3:List of Experimental Equipment and Materials:
FTO coated glass substrates (TCO 22-7), Aeroxide TiO2 P25 nanoparticles, non-ionic surfactant binder (Triton X-100), particle stabiliser (acetylacetone), de-ionised water or tert-butanol as the solvent, Ruthenizer 535-bisTBA an N719 dye, Platisol-T, Iodide/Iodine (I-/I3-) redox solution.
4:Experimental Procedures and Operational Workflow:
The TiO2 formulation was either screen printed or spray coated onto the FTO coated glass substrates and cured at 150 oC and 450 oC for 30 minutes, respectively. Then the dye loading process is carried out by immersing the samples into the pre-mixed dye solution for 24 hours. The last stage is to assemble the device by depositing the liquid electrolyte and sandwiching the two electrodes for testing.
5:Data Analysis Methods:
The morphology of the prepared sample photo anodes were analysed using field emission scanning electron microscopy (FESEM). After dye loading and assembly, photocurrent and voltage measurements were performed on the assembled sample cells using a Keithley 2400 source meter under an ABET 1 Sun Simulator with 1.5 AM radiation for the fabricated DSSCs.
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Keithley 2400 source meter
2400
Keithley
Used for photocurrent and voltage measurements of the assembled sample cells.
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FTO coated glass substrates
TCO 22-7
Solaronix
Used for the photo anode and cathode in DSSCs.
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Aeroxide TiO2 P25 nanoparticles
P25
Sigma Aldrich
Used as the nano-crystalline material for the TiO2 film in DSSCs.
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Triton X-100
Sigma Aldrich
Non-ionic surfactant binder used in the TiO2 formulations.
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Acetylacetone
Sigma Aldrich
Particle stabiliser used to prevent the nanoparticles aggregating in the complex suspension system.
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Ruthenizer 535-bisTBA an N719 dye
N719
Solaronix
Used as the dye sensitizer in DSSCs.
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Platisol-T
Solaronix
Used as the precursor of the platinum layer for the counter cathode in DSSCs.
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Iodide/Iodine (I-/I3-) redox solution
Solaronix
Used as the liquid electrolyte in DSSCs.
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ABET 1 Sun Simulator
ABET
Used to simulate 1.5 AM radiation for testing the fabricated DSSCs.
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TEPLA Plasma 300 machine
Plasma 300
TEPLA
Used for plasma cleaning the FTO glass substrates.
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