研究目的
Investigating the influence of TCO substrates on the solar cell characteristics of SnGe-perovskite solar cells.
研究成果
The efficiency of the SnGe-perovskite solar cell is highest with FTO with texture substrate, mainly due to the improvement in the Jsc, which is attributed to the higher transmittance of FTO substrate. The Voc is slightly lower than that of Flat ITO substrate due to the deeper work function of Flat ITO substrate. The study provides a basis for fabricating higher efficiency solar cells while keeping the fabrication cost low.
研究不足
The study does not provide a clear conclusion on the effect of relative strain and grain size on the device performance. Additionally, the surface roughness of the substrates did not directly influence the device performance as much as the substrate’s transmittance and work function.
1:Experimental Design and Method Selection:
The study investigates the influence of different TCO substrates (Flat ITO, Flat FTO, and FTO with texture) on the efficiency of SnGe-perovskite solar cells.
2:Sample Selection and Data Sources:
SnGe-perovskite solar cells were fabricated on three different TCO substrates.
3:List of Experimental Equipment and Materials:
Materials include Tin (II) iodide, Tin (II) fluoride, Germanium (II) iodide, Formamidinium iodide, N,N-Dimethylformamide, Dimethyl sulfoxide, and other solvents. Equipment includes a Rigaku Smartlab X-ray diffractometer, JASCO V-670 Spectrophotometer, Keithley 4200 source meter, solar simulator, and a scanning probe microscope.
4:Experimental Procedures and Operational Workflow:
The TCO glass substrates were cleaned and treated with oxygen plasma. PEDOT:PSS was spin-coated on the substrates, followed by the perovskite precursor solution. The films were annealed, and layers of C60, BCP, Ag, and Au were sequentially evaporated.
5:Data Analysis Methods:
The performance of the solar cells was analyzed using J-V curves, UV-VIS spectrum measurement, impedance spectroscopy, and atomic force microscopy.
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Tin (II) iodide
SnI2
Sigma Aldrich
Used in the preparation of perovskite film
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Tin (II) fluoride
SnF2
Sigma Aldrich
Used in the preparation of perovskite film
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Germanium (II) iodide
GeI2
Sigma Aldrich
Used in the preparation of perovskite film
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Formamidinium iodide
FAI
TCI
Used in the preparation of perovskite film
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N,N-Dimethylformamide
DMF
Sigma Aldrich
Solvent used in the preparation of perovskite film
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Dimethyl sulfoxide
DMSO
Sigma Aldrich
Solvent used in the preparation of perovskite film
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Rigaku Smartlab X-ray diffractometer
Rigaku
Used for obtaining XRD patterns
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JASCO V-670 Spectrophotometer
JASCO
Used for UV-VIS spectrum measurement
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Keithley 4200 source meter
Keithley
Used for solar cell measurement
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Solar simulator
Bunkoukeiki
Used for solar cell measurement under 100 mWcm-2 AM 1.5G
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Scanning probe microscope
JSPM-5200
Used for obtaining atomic force microscopy images
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