研究目的
To improve the efficiency of a CdSe Quantum Dot Sensitized Solar Cell (QDSSC) by F?rster Resonance Energy Transfer (FRET) mechanism using graphene quantum dots (GQD) as energy donors.
研究成果
The FRET between GQD as donor and CdSe as acceptor has been successfully explored in a QDSSC, showing an efficiency enhancement of 55%. The study provides new insights for selective light harvesting of the solar spectrum for future applications.
研究不足
The efficiency of the QDSSC presented in this FRET system is low, and the study is limited to the UV region of the electromagnetic spectrum.
1:Experimental Design and Method Selection:
The study utilized FRET mechanism between GQD (donor) and CdSe (acceptor) to enhance the efficiency of QDSSC.
2:Sample Selection and Data Sources:
CdSe quantum dots and GQDs were synthesized and characterized for their optical properties.
3:List of Experimental Equipment and Materials:
Materials included cadmium chloride, selenium, 3-mercaptopropionic acid (MPA), L Ascorbic acid, TiO2 nanoparticles, fluorine doped tin oxide (FTO), hexachloroplatinic acid, potassium iodide, and N719 dye. Equipment included UV–vis spectrophotometer, transmission electron microscopy (TEM), Fourier transform infrared spectra (FTIR) spectrometer, photoluminescent (PL) measurements setup, and solar simulator.
4:Experimental Procedures and Operational Workflow:
The FTO glass plates were cleaned, doctor bladed with TiO2 paste, sintered, and then sensitized with CdSe and GQDs. The solar cells were assembled and their performance was measured.
5:Data Analysis Methods:
The FRET parameters were calculated using spectral overlap integral, quantum yield, and lifetime measurements.
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Transmission electron microscopy
Jeol/JEM 2100
Jeol
Determine the size of the synthesized nanoparticles.
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Fourier transform infrared spectra spectrometer
PerkinElmer Spectrum Two
PerkinElmer
Measure FTIR spectra of GQDs and CdSe.
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Photoluminescent measurements setup
PerkinElmer LS 55
PerkinElmer
Conduct PL measurements in the visible range.
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UV–vis spectrophotometer
T90
PG Instruments
Measure the nature of absorbance of the nanoparticles in the visible range of the solar spectrum.
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Solar simulator
Scientech
Scientech
Measure the performance of DSSC under 1 sun illumination.
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Flurocube-lifetime system
JOBIN-VYON
JOBIN-VYON
Measure lifetimes of the samples using pulsed diode excitation of 370 nm.
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