研究目的
Investigating the response properties of gold- and aluminum-deposited SPR-based glass rod sensors using light-emitting diodes with various wavelengths.
研究成果
The study demonstrated the potential and usefulness of the multi-layer Fresnel equation for estimating the performance of SPR-based glass rod sensors. It was found that the ratio of the real and imaginary parts of the dielectric constant provides a simple and useful estimation for SPR. The agreements between experimental and theoretical response curves validate the theoretical approach for both Au and Al films, including the consideration of native oxide layers on Al.
研究不足
The study acknowledges the experimental uncertainties, especially with the near-infrared LED due to its wide wavelength distribution. The theoretical calculations assume a constant thickness for the native oxide layer on Al films, which may not account for variations in actual conditions.
1:Experimental Design and Method Selection:
The study involved measuring the response curves of SPR-based glass rod sensors with Au and Al films of various thicknesses using LEDs of different wavelengths. Theoretical calculations were performed using a multi-layer Fresnel equation with various dielectric constants.
2:Sample Selection and Data Sources:
Glass rods of 2 mm in diameter with Au and Al films deposited on half of their surfaces were used as sensor elements. The response curves were measured using methanol solutions of ethylene glycol.
3:List of Experimental Equipment and Materials:
Equipment included LEDs of various wavelengths, a mini-spectrometer, a DC stabilized power supply, and an Abbe refractometer. Materials included glass rods, Au and Al for deposition, and ethylene glycol solutions.
4:Experimental Procedures and Operational Workflow:
The sensors were constructed by fixing the sensor elements in a glass tube with Teflon tubes for sample inflow and outflow. The response curves were measured by introducing ethylene glycol solutions into the sensor cell at a flow rate of 0.1 mL/s.
5:1 mL/s. Data Analysis Methods:
5. Data Analysis Methods: The theoretical response curves were calculated considering the LED intensity distribution, the angle of light incidence, and the thickness distributions of the metal films. The experimental and theoretical response curves were compared.
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LED
SLA-560LT-3F
ROHM
Light source for SPR sensor
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Mini-spectrometer
C10083MD
浜松ホトニクス
Measurement of emission spectra
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LED
OSSV5111A
OptoSupply
Light source for SPR sensor
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LED
YC-5046CC
海渡電子
Light source for SPR sensor
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LED
5SG4SC-LG
海渡電子
Light source for SPR sensor
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LED
YCL-513UYC-TS
海渡電子
Light source for SPR sensor
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LED
OSIR5113A
OptoSupply
Light source for SPR sensor
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DC stabilized power supply
R6144
ADC
Power supply for LEDs
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Abbe refractometer
RX-5000α-BeV
アタゴ
Measurement of sample refractive index
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