研究目的
Investigating the effect of fluxes on the luminescence properties of color-tunable Ba1.3Ca0.7SiO4:Eu2+, Mn2+ phosphor for near-ultraviolet white-LEDs.
研究成果
The BaCl2 flux effectively enhances Mn2+ doping into the BCS lattice and affects the tunable emission color depending on the BaCl2 amount. The phosphor with SrCl2 exhibits excellent optical properties with a CRI of 87.2, a CCT of 4905 K, and CIE chromaticity coordinates of (0.347, 0.343). NH4Cl shows the best fluxing effect for Mn2+ doping.
研究不足
The study focuses on the effect of fluxes on the luminescence properties of the phosphor but does not extensively explore the reaction mechanism between each type of flux and starting materials or the influence factors of luminescence properties such as crystal defects and particle morphology.
1:Experimental Design and Method Selection:
The phosphor samples were prepared by the high-temperature solid-state reaction method at a calcination temperature of 1000 °C for 2 h in a reducing atmosphere (mixture of 5%H2–95%N2). Different fluxes were added to investigate their effects on the phase formation and luminescence properties.
2:2). Different fluxes were added to investigate their effects on the phase formation and luminescence properties. Sample Selection and Data Sources:
2. Sample Selection and Data Sources: Commercially available BaCO3, CaCO3, MnCO3, and Eu2O3 were used as starting materials.
3:List of Experimental Equipment and Materials:
Powder X-ray diffraction (XRD, D/MAX-Ultima, Rigaku) for structure and phase analysis, and a fluorescence spectrophotometer (EVERFINE, EX-1000, China) for photoluminescence properties measurement.
4:Experimental Procedures and Operational Workflow:
The phosphor samples were annealed at 1000 °C for 2 h. The structure and phase were analyzed by XRD, and photoluminescence properties were measured under excitation by a 365 nm source.
5:Data Analysis Methods:
The emission spectra, CIE chromaticity coordinates, and CRI were analyzed based on the photoluminescence spectra.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容