研究目的
Investigating the enhancement of emission intensity in Dy3+-doped ZnO/ZnF2 phosphoborate glasses for W-LED materials.
研究成果
The substitution of ZnO with ZnF2 in Dy3+-doped zinc phosphoborate glasses enhances the emission intensity, particularly at 573 nm, making these glasses suitable candidates for W-LED and lighting materials. The Judd-Ofelt parameters indicate a similar site around Dy3+ ions, beneficial for optical applications. The glasses emit white light, as confirmed by CIE chromaticity coordinates, and exhibit suitable color temperatures for warm white light applications.
研究不足
The study focuses on the effect of ZnF2 substitution on the optical properties of Dy3+-doped glasses but does not explore the thermal stability or mechanical properties of the glasses. The practical application in W-LEDs may require further optimization of glass composition and processing conditions.
1:Experimental Design and Method Selection:
The study involved the preparation of Dy3+-doped zinc phosphoborate glasses by replacing ZnO with ZnF2 using the melt quenching method. The optical absorption and photoluminescence properties were investigated to understand the effect of ZnF2 on the emission intensity.
2:Sample Selection and Data Sources:
Glasses with compositions 49B2O3:30P2O5:(20-x)ZnO:xZnF2:1Dy2O3, where 0 ≤ x ≤ 20 mol%, were prepared. The samples were characterized using UV-VIS-NIR spectrophotometry and fluorescence spectrophotometry.
3:List of Experimental Equipment and Materials:
Equipment included a Shimadzu UV3600 UV-VIS-NIR spectrophotometer and a Cary Eclipse fluorescence spectrophotometer. Materials included B2O3, P2O5, ZnO, ZnF2, and Dy2O
4:Experimental Procedures and Operational Workflow:
The glasses were melted at 1200°C for 3 hours, quenched, and annealed. Optical absorption and photoluminescence spectra were measured to analyze the effects of ZnF2 substitution.
5:Data Analysis Methods:
The Judd-Ofelt theory was applied to calculate intensity parameters from absorption spectra. Emission spectra were analyzed to determine radiative properties and color coordinates.
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