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Abnormal scaling of excitons in phosphorene quantum dots

DOI:10.1039/c9cp06146k 期刊:Physical Chemistry Chemical Physics 出版年份:2020 更新时间:2025-09-23 15:19:57
摘要: Excitonic states of a many-electron system in phosphorene quantum dots (PQDs) are investigated theoretically by using a configuration interaction approach. For a triangular PQD in various dielectric environments, its exciton is found to obey two distinct scaling rules. When there is strong screening effect present in the nanodot, the exciton binding energy (?ex) is shown to be around ?150 meV as the long-range Coulomb interactions are totally suppressed and increases to about 100 meV when the effective dielectric constant (εr) decreases to 12.5. Over this range of εr, ?ex is found to be well fitted into a quadratic form of ε?1 r like the case of bulk three-dimensional semiconductors nor linearly with ε?1 r like the case previously reported for graphene nanostructures. When εr is reduced below 10.0, however, ?ex is shown to exhibit a perfect linear relation with ε?1 r, which behaves just like that of a two-dimensional graphene sheet. On the other hand, with the reduced εr, the quasiparticle gap is found to decrease instead of increase like in most of semiconductor nanostructures. As a result, it is revealed that the relationship of ?ex with the quasi-particle gap deviates largely from the linear one previously reported for graphene and many other two-dimensional materials.
作者: Jun Zhong,Linan Huang,Weidong Sheng
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Investigating the excitonic states of a many-electron system in phosphorene quantum dots (PQDs) and their dependence on the dielectric environment.

The study reveals that excitons in phosphorene quantum dots exhibit an abnormal scaling rule that lies between those of conventional 3D semiconductors and 2D materials like graphene. The exciton binding energy shows a quadratic dependence on the inverse of the effective dielectric constant for strong screening effects and a linear dependence for weak screening. The quasiparticle gap decreases with reduced dielectric constant, contrary to most semiconductor nanostructures, and the relationship between the exciton binding energy and the quasiparticle gap deviates from the linear one observed in other 2D materials.

The study is theoretical and does not account for experimental variations or imperfections in real phosphorene quantum dots. The model assumes a perfect triangular shape and does not consider edge defects or impurities.

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