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Fullerenea??Based Interlayers for Breaking Energy Barriers in Organic Solar Cells

DOI:10.1002/cplu.202000082 期刊:ChemPlusChem 出版年份:2020 更新时间:2025-09-23 15:19:57
摘要: Organic solar cells (OSCs) are lightweight, flexible, and have easy solution processability, thus making them advantageous for large-area device fabrication. The interlayer materials between the electrodes and organic active layer are vital elements for device fabrication. Recently, solution-processable fullerene derivatives have been studied intensively as efficient electrode interlayer materials for solar cell applications. In this Minireview, we summarize recent advances using fullerene derivatives as interlayers in OSCs. The examples include fullerene interlayers from small molecules to polymers, and to organic composites or organic/inorganic hybrid materials. We focus on the comprehensive efforts in developing fullerene-based interlayers and present the understanding of multiple functionalities of these materials as cathode interlayers in bulk hetero-junction (BHJ) OSCs. Our motivation is to describe our current understanding, recent progress, and outstanding issues of fullerene interlayers in OSCs, and propose future potential directions and opportunities.
作者: Ying Gu,Yao Liu,Thomas P. Russell
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To summarize recent advances using fullerene derivatives as interlayers in OSCs, focusing on the comprehensive efforts in developing fullerene-based interlayers and presenting the understanding of multiple functionalities of these materials as cathode interlayers in bulk hetero-junction (BHJ) OSCs.

The review concludes that despite significant progress in the development of fullerene-based interlayers, much work remains to fully understand their functions and optimize their performance in OSCs. It suggests future directions for research, including the development of new methods and models for achieving fullerenes with more tunable energy levels and the optimization of interlayer structures for compatibility with non-fullerene acceptors.

The review highlights the need for a deeper understanding of the multiple functions of fullerene interlayers, their chemical stability, and the stability of their morphology during device operation. It also points out the challenges in matching the energy levels of non-fullerene acceptors and the need for further structural optimization of fullerene-based interlayers.

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