摘要： Organic optoelectronic materials can be generally divided into small molecular weight semiconductors and conjugated polymers with high opto/electronic performance. This interesting electroluminescence and conducting properties were first discovered in the 1970s, but the real surge of the interest occurred in the past 20 years with significant improvements in material performance through creative material design and high material purification. Small molecular weight semiconductors are interesting because of their high purity, ordered structures, and ideal model for fundamental mechanism studies of excitons and charge carriers. Conjugated polymers are mainly used for device fabrication for their advantages of large‐area device fabrication, high performance, and multiple functions. Currently, organic materials receive considerable attention because of their successful applications in organic light‐emitting diodes (OLEDs), solar cell, liquid crystal display (LCD), thin film transistors, sensors, electrochromic devices, and many others. Thanks to the extensive academic and industrial efforts, the mechanism and the relationship between the molecular structure and optoelectronic properties have been illustrated, and various device structures have been developed. Although organic optoelectronic materials have experienced tremendous progress over the past 10 years in fundamental physics and real applications, more work is necessary such as theoretical descriptions in charge generation and transport, distinction in the contributions of various interactions, thermal stability improvement, and commercialization of existing applications. Various new phenomena are still being discovered every day and device performance is continuing to rise. Among these efforts, the incorporation of polyhedral oligomeric silsesquioxanes (POSSs) into organic optoelectronic materials to achieve improved performances has been attracting attention particularly because of the unique and interesting hybrid structures of POSS.