研究目的
Investigating the impact of interstitial Fe contamination on the effective minority carrier lifetime of n-type Cz silicon bulk material for high efficiency solar cells.
研究成果
The study demonstrates that interstitial Fe contamination significantly degrades the effective minority carrier lifetime and solar cell efficiency, even at very low concentrations. The findings support the use of the SRH theory for modeling Fe contamination effects and highlight the importance of controlling Fe contamination in solar cell manufacturing.
研究不足
The study is limited to n-type Cz silicon material and focuses on interstitial Fe contamination. The impact of other metal impurities or contamination sources is not considered.
1:Experimental Design and Method Selection:
The study involves intentionally contaminating a wet chemical process tank with Fe to mimic contamination during solar cell manufacturing. The transfer of Fe to the silicon wafer surface is measured, and the wafers are passivated with thermal silicon oxide. The surface contamination is driven into the bulk by a high temperature process. Effective minority carrier lifetime is measured at various injection levels.
2:Sample Selection and Data Sources:
Commercially available n-type large-area semi-square Cz-Silicon material is used. Fe contamination levels are measured using VPD-DC-TXRF.
3:List of Experimental Equipment and Materials:
A 13l quartz beaker for the contamination bath, thermal oxidation process equipment, and a BT Imaging tool for QSSPC measurements.
4:Experimental Procedures and Operational Workflow:
Wafers are cleaned, contaminated with Fe, passivated, and then subjected to a high temperature process. Effective minority carrier lifetime is measured and compared to non-contaminated samples.
5:Data Analysis Methods:
The SRH theory is used to fit the measured lifetime curves and extract Fe contamination concentration and capture cross section. QUOKKA simulations are used to predict solar cell efficiencies based on the extracted data.
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