研究目的
Investigating the optoelectrical properties of doped hydrogenated nanocrystalline silicon oxide layers for high-efficiency c-Si heterojunction solar cells.
研究成果
The study demonstrates the potential of nc-SiOx:H layers for high-efficiency c-Si heterojunction solar cells. Interface treatments significantly improve the electrical properties and passivation quality, leading to higher fill factors and conversion efficiencies. The optical effectiveness of nc-SiOx:H-based contact stacks is confirmed by higher short-circuit current densities and cell efficiencies compared to a-Si:H.
研究不足
The study focuses on thin layers (less than 20 nm) and the challenge of achieving high conductivity while preserving c-Si passivation quality. The impact of different surface treatments on the nucleation of nanocrystals and passivation quality is also a limitation.
1:Experimental Design and Method Selection:
The study involves the use of plasma-enhanced chemical vapor deposition (PECVD) to deposit doped nc-SiOx:H layers on Corning Eagle XG glass. The evolution of optoelectrical parameters is investigated by varying the main deposition conditions.
2:Sample Selection and Data Sources:
Double-side textured float-zone (FZ) <100> c-Si wafers with resistivity of 3 ± 2 Ω cm and thickness of 280 ± 20 μm are used.
3:List of Experimental Equipment and Materials:
PECVD system, spectroscopic ellipsometry (SE), temperature-dependent I-V setup, Fourier-transform infrared (FTIR) spectroscopy, Sinton WCT-120, Wacom WXS-156S-L2 solar simulator.
4:Experimental Procedures and Operational Workflow:
The deposition time is adapted for tilted pyramids using the geometrical factor of
5:Interface treatments and post-treatments are applied to improve the electrical properties and passivation quality. Data Analysis Methods:
The optoelectrical parameters are analyzed using SE, FTIR spectroscopy, and I-V measurements.
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