研究目的
To develop a nanoplatelet-based light emitting diode (LED) with high quantum efficiency, low turn-on voltage, and long-term stability for use in all-nanocrystal LiFi-like communication.
研究成果
The developed LED based on core/shell NPLs grown at high temperature achieves a maximal EQE of 5.15% with a record low turn-on voltage of 1.63 V and long lifetime (3160 h at 100 cd.m-2). The LED's performance in a LiFi-like communication setup demonstrates the potential for all nanocrystal-based communication systems.
研究不足
The study is limited by the PL efficiency of the NPLs (around 35%) and the efficiency droop observed under high current injection. The temperature-dependent shift in transport and EQE suggests that future improvements should focus on the transport layers.
1:Experimental Design and Method Selection:
The study involves the synthesis of CdSe/CdZnS core/shell nanoplatelets (NPLs) with optimized shell alloy content for hole injection in LED structures. High-temperature shell growth is chosen over low-temperature methods for higher quantum efficiency.
2:Sample Selection and Data Sources:
CdSe core NPLs are synthesized and coated with CdZnS shells. The shell composition is varied to optimize the LED performance.
3:List of Experimental Equipment and Materials:
Includes transmission electron microscopy for NPL characterization, X-ray photoemission spectroscopy for electronic structure analysis, and various chemicals for NPL synthesis and LED fabrication.
4:Experimental Procedures and Operational Workflow:
The LED fabrication involves spin-coating layers of PEDOT:PSS, Poly-TPD, PVK, NPLs, and ZnO nanoparticles on ITO substrates, followed by Ag electrode deposition.
5:Data Analysis Methods:
The performance of the LED is evaluated through electroluminescence spectra, current-voltage-luminance characteristics, and external quantum efficiency measurements.
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Si Detector
S120C
Thorlabs
Used for characterization.
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Transmission Electron Microscope
JEOL 2010
JEOL
Used to observe the nanocrystals.
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UV-Visible Spectrometer
JASCO V-730
JASCO
Used for UV-Visible spectroscopy.
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Sourcemeter Unit
Keithley K2634B
Keithley
Used to collect current-voltage-luminance characteristics.
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Powermeter
PM100A
Thorlabs
Coupled with the S120C Si detector for characterization.
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Photoluminescence Spectrometer
Edinburgh Instrument
Used to obtain photoluminescence (PL) spectra and PL quantum yield in a solution sample.
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X-ray Photoemission Spectrometer
SCIENTA SES2002
SCIENTA
Used for ultraviolet photoemission spectroscopy.
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Lock-in Amplifier
MFLI
Used to drive the LED and measure the detected signal from the PbS solar cell.
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Transimpedance Amplifier
DLPCA-100
Femto
Used to amplify the current from the solar cell.
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