研究目的
To develop a sustainable and low-cost design for metal-free wearable solar cell devices using all carbon dye sensitized solar cells (C-DSSC).
研究成果
The study successfully demonstrated a facile and efficient method for fabricating wearable all carbon dye sensitized solar cells (C-DSSC) with a power conversion efficiency of ~6%. The use of carbon-based electrodes offers a sustainable and low-cost alternative to traditional metal-based solar cells, with potential applications in wearable technology. Future work is directed towards improving the stability and efficiency of C-DSSC.
研究不足
The study mentions the need for optimization in stability and power conversion efficiency (PCE) of C-DSSC, indicating current limitations in these areas. Additionally, the thickness and flexibility requirements may impose constraints on the scalability and durability of the devices.
1:Experimental Design and Method Selection:
The study involves the fabrication of carbon front electrodes (CFE) and carbon counter electrodes (CCE) for C-DSSC. CFE was fabricated using a wet laid web method, and CCE was dip-coated with graphene ink. TiO2 nanorods (P25-R) were synthesized via hydrothermal technique for deposition over CFE.
2:Sample Selection and Data Sources:
Carbon fiber wetlaid web sheets and graphene oxide nanosheets were used as primary materials.
3:List of Experimental Equipment and Materials:
Conductive transparent fluorinated tin oxide glass (FTO TEC 8, Pilkington Co), carbon short-cut fiber (CF, 7 μm x 6 mm, PAN type, Toray Chem.), Poly(ethyleneimine) binder, P25 (25 nm sized, Degussa Co.), sodium hydroxide (NaOH), graphene ink synthesized from graphite powder, and polyvinylidene difluoride (PVDF) for the spacer.
4:Experimental Procedures and Operational Workflow:
Fabrication of CFE with varying carbon fiber content, synthesis of TiO2 nanorods, fabrication of Gr@CCE by dip-and dry coating technique, and assembly of C-DSSC with PVDF membrane spacer.
5:Data Analysis Methods:
Characterization included UV-1650PC spectrophotometer for light transmission spectra, four-point probe head system for sheet resistance, FE-SEM for surface morphology, XRD for crystal structure, CV and EIS for electrocatalytic performance, and solar simulator for photovoltaic performance.
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