研究目的
Investigating the enhancement of power conversion efficiency in perovskite solar cells through the incorporation of aluminium nanoparticles at the PC61BM/Al electrode interface to improve light harvesting via plasmonic and scattering effects.
研究成果
The incorporation of aluminium nanoparticles at the PC61BM/Al interface in perovskite solar cells leads to a significant improvement in power conversion efficiency, primarily due to enhanced optical absorption from plasmonic and scattering effects, and reduced series resistance. This approach offers a promising pathway for the development of high-efficiency perovskite photovoltaic devices.
研究不足
The study focuses on the effects of AlNPs on perovskite solar cells but does not explore the long-term stability or scalability of the modified devices. The particle size distribution and its precise control could also be a limitation for consistent performance enhancement.
1:Experimental Design and Method Selection:
The study involved the fabrication of CH3NH3PbI3 perovskite solar cells with and without aluminium nanoparticles (AlNPs) at the PC61BM/Al interface to investigate the effects on optical absorption and device performance.
2:Sample Selection and Data Sources:
The samples included perovskite solar cells with a modified PC61BM layer embedded with AlNPs. Optical and electrical properties were measured to assess performance.
3:List of Experimental Equipment and Materials:
Materials included ITO coated glass, PEDOT:PSS, CH3NH3PbI3, PC61BM, and AlNPs. Equipment used were UV-Visible spectrometer, X-ray diffractometer, AFM, TEM, and solar simulator.
4:Experimental Procedures and Operational Workflow:
The fabrication process involved spin-coating layers of PEDOT:PSS, CH3NH3PbI3, and PC61BM with or without AlNPs, followed by thermal evaporation of aluminium electrodes. Characterization included optical absorption, PL emission, and photovoltaic measurements.
5:Data Analysis Methods:
Data analysis involved comparing the optical and electrical properties of devices with and without AlNPs to determine the impact on power conversion efficiency.
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Poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate)
PEDOT:PSS(Al4083)
Heraeus Precious Metal GmbH & Co
Used as a hole transport layer in the solar cell.
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UV-Visible spectrometer
Lambda35
PerkinElmer
Used to study optical absorption and transmission properties.
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X-ray diffractometer
SmartLab
Rigaku
Used for X-ray diffraction measurement of aluminium nanoparticles.
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AFM
Easy scan
Nanosurf
Used to study surface morphology.
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ITO coated glass substrate
Xin-Yan Technology Limited
Used as a transparent conductive substrate for the solar cell.
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bis-[6,6]-phenyl C61 butyric acid methyl ester
PC61BM
Nano-C Corporation
Used as an electron transport layer in the solar cell.
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Lead iodide
PbI2
Alfa Aesar
Used as a precursor for the perovskite active layer.
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Methyl ammonium iodide
MAI
Dysol Inc
Used as a precursor for the perovskite active layer.
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Aluminium wire
Sigma Aldrich
Used for thermal evaporation to deposit aluminium electrodes.
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TEM
Used to study nanoparticle size distribution and morphology.
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Solar simulator
Newport
Used to simulate AM1.5G light condition.
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Quantum efficiency measurement system
QE-R EQE system
Enli-Tech Co., Ltd
Used for quantum efficiency measurement.
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