研究目的
Investigating the correlation between the open-circuit voltage and recombination loss at metal-silicon interfaces of crystalline silicon solar cells.
研究成果
The study quantitatively assessed the recombination in the metallized area, highlighting the effects of the doping profile of the emitter region and silver crystallites on surface recombination. It was found that Jo.metal increased with increasing surface doping concentration and firing temperature, leading to a decrease in Voc. The amount of silver crystallites on the silicon wafer was quantitatively analyzed, showing a direct correlation with recombination loss.
研究不足
The extraction of Jo.metal using QSSPC measurements was less accurate in the low injection region due to the effect of surface recombination. This behavior became worse at higher firing temperatures.
1:Experimental Design and Method Selection:
The study involved analyzing the contact characteristics of a screen-printed silver electrode and silicon interface using saturation current density (Jo) measurements according to the surface doping concentration and firing temperature.
2:Sample Selection and Data Sources:
Silicon substrates were p-type Cz wafers with a resistivity of 1 ~ 3 Ω cm and a thickness of ~180 μm. Samples were doped with phosphorous on both sides to form emitter layers with varying sheet resistances.
3:List of Experimental Equipment and Materials:
Equipment included a tube furnace for doping, SEM and TEM for observing Ag crystallites, ICP-OES for Ag concentration analysis, and QSSPC for Jo measurements.
4:Experimental Procedures and Operational Workflow:
Samples were prepared with different doping profiles, passivation layers were deposited, and metal electrodes were formed using screen printing followed by firing. Jo values were obtained from QSSPC measurements.
5:Data Analysis Methods:
Jo.metal was extracted by fitting Jo at a high injection level. The effect of Jo.metal on Voc was analyzed by calculating changes in surface recombination velocity.
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