研究目的
To develop a new host material with well-matched triplet energy levels to phosphorescent red emitter and present a simple approach to inkjet print the binary small-molecule electrophosphorescent blend with the single solvent.
研究成果
The study successfully developed a new host material compatible with a red phosphorescent dopant for inkjet printing. By optimizing the solvent and substrate, uniform film morphology was achieved without the coffee ring effect. The OLEDs with the inkjet-printed emitter showed a maximum current efficiency comparable to those with spin-cast emitters, demonstrating the potential of inkjet printing for fabricating high-performance OLEDs.
研究不足
The study focuses on the inkjet printing of a specific binary small-molecule electrophosphorescent blend and its performance in OLEDs. The limitations include the dependency on the choice of solvents and substrates for achieving uniform film morphology and the need for optimization of the inkjet printing process for different materials.
1:Experimental Design and Method Selection:
The study involved the synthesis of a new host material and its compatibility with a red phosphorescent dopant for inkjet printing. The methodology included the use of single solvent systems to achieve uniform film morphology.
2:Sample Selection and Data Sources:
The host material and dopant were synthesized and characterized. The ink solutions were prepared with various solvents to study their printability and film morphology.
3:List of Experimental Equipment and Materials:
Instruments used include Bruker 500 MHz DRXspectrometers for NMR, Waters ACQUITY TQD for mass spectroscopy, Netzsch TG 209 for TGA, Netzsch DSC 204 for DSC, HP 8453 UV-Vis spectrophotometer, HORIBA Fluorogo-3 fluorescence spectrophotometer, CHI660A electrochemical workstation, Brookfield Rotational Viscometer, OneAttension Theta Lite for surface tension and contact angle measurements, JetLab II printer for inkjet printing, Dektak 150 surface profiler, and Veeco NT 9300 for surface morphology characterization.
4:Experimental Procedures and Operational Workflow:
The host material was synthesized and characterized. Ink solutions were prepared and their printability was tested on different substrates. The OLED devices were fabricated and their performance was evaluated.
5:Data Analysis Methods:
The film morphology was analyzed using surface profilers and AFM. The OLED performance was evaluated using current density-voltage-luminance measurements and EL spectra analysis.
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Bruker 500 MHz DRXspectrometers
Bruker
NMR measurements
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Waters ACQUITY TQD
Waters
Mass spectroscopy
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Netzsch TG 209
Netzsch
Thermogravimetric analysis
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Netzsch DSC 204
Netzsch
Differential scanning calorimetry
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HP 8453 UV-Vis spectrophotometer
HP
UV-Vis absorption spectra recording
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HORIBA Fluorogo-3
HORIBA
PL spectra measurement
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CHI660A electrochemical workstation
Cyclic voltammetry
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Brookfield Rotational Viscometer
LVDV-I+
Brookfield
Viscosity measurement
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OneAttension Theta Lite
TL100
Surface tension and contact angle measurement
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JetLab II printer
MicroFab Technologies, Inc.
Inkjet printing
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Dektak 150 surface profiler
Bruker Corp.
Surface morphology characterization
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Veeco NT 9300
Veeco
Surface morphology characterization
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