摘要： Two structural isomers of alkyl-substituted tri-carbazoles were synthesised to study the effect of the substitution pattern on their liquid crystalline behaviour and conductivity and performance in test OLEDs. The isomer with a 2,7-disubstitution pattern in the central carbazole exhibits a monotropic nematic phase, a high conductivity up to 10 Cd A?1 and is suitable as a hole-transport material for solution-processed OLEDs, achieving a high efficiency. The tri-carbazole isomer with a 3,6-substitution pattern, in the central carbazole, does not exhibit observable liquid crystalline behaviour, exhibits conductivity values two orders of magnitude lower than that of its 2,7-disubstituted isomer and performs poorly in OLEDs with the same configuration. Two structural isomers of alkyl-substituted tri-carbazoles A and B exhibit significantly different liquid crystalline behaviour, conductivity and performance in test OLEDs dependent upon their molecular shape.