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Influences of Low Intensity on Diode Parameters of CdTe Solar Cells

DOI:10.3390/ma13092194 期刊:Materials 出版年份:2020 更新时间:2025-09-23 15:21:01
摘要: This study deals with the CdS/CdTe solar cells under low illumination intensity, with cell #1 for the shunt resistance exceeding 100,000 ?·cm2 and cell #2 for the shunt resistance above 1000 ?·cm2. The diode parameter variations with the decline of the irradiance intensity are illustrated by dividing 0–100 mW/cm?2 into a number of small intensity ranges for J–V measurements and assuming the diode parameters to be constant within each range, the diode parameters of each range including the series resistance, the shunt resistance, the reverse saturation current density and the ideality factor are then extracted by employing an analytical approach. The mechanism of the cell performance deviations are also investigated by basic theories, reports and experiments. For cell #1 with higher Rsh corresponding to less traps, Rsh shows a upward tendency as the irradiance declines, n and J0 exhibit a rise with the irradiance and keep nearly unchanged at the low irradiance values mainly due to recombination and carrier contributions, Rs shows a slight increase when the irradiance intensity goes down because of the resistance of CdTe absorption layer. For cell #2 with lower Rsh corresponding to more traps, with the decrease of the illumination intensity, Rsh increases sharply only for captured carrier reduction, Rs goes steadily up similarly, n and J0 exhibit a decline with the irradiance due to recombination shift. It should be pointed out that Rs varies much smoother than the traditional approximation of a reciprocal of di?erential at short circuit, and the distribution of Rsh is diverse, and an average Rsh of for each intensity range can re?ect the variation trend.
作者: Xiaobo Xu,Wenping Gu,Xiaoyan Wang,Wei Zhu,Lin Zhang,Zan Zhang
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Investigating the diode parameter variations of CdTe solar cells under low irradiance intensity.

The study concludes that diode parameters of CdTe solar cells vary significantly with low irradiance intensity, influenced by recombination mechanisms and carrier contributions. For cells with higher shunt resistance, parameters show a steady increase with decreasing irradiance, while cells with lower shunt resistance exhibit more complex behavior. The findings provide valuable insights for the design and fabrication of CdTe solar cells under low light conditions.

The study is limited to CdTe solar cells under low illumination intensity conditions. The accuracy of parameter extraction may be affected by measurement uncertainties, especially at very low irradiance levels (<20 mW/cm2).

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