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Distance-Resolving Raman Radar Based on a Time-Correlated CMOS Single-Photon Avalanche Diode Line Sensor

DOI:10.3390/s18103200 期刊:Sensors 出版年份:2018 更新时间:2025-09-23 15:21:21
摘要: Remote Raman spectroscopy is widely used to detect minerals, explosives and air pollution, for example. One of its main problems, however, is background radiation that is caused by ambient light and sample fluorescence. We present here, to the best of our knowledge, the first time a distance-resolving Raman radar device that is based on an adjustable, time-correlated complementary metal-oxide-semiconductor (CMOS) single-photon avalanche diode line sensor which can measure the location of the target sample simultaneously with the normal stand-off spectrometer operation and suppress the background radiation dramatically by means of sub-nanosecond time gating. A distance resolution of 3.75 cm could be verified simultaneously during normal spectrometer operation and Raman spectra of titanium dioxide were distinguished by this system at distances of 250 cm and 100 cm with illumination intensities of the background of 250 lux and 7600 lux, respectively. In addition, the major Raman peaks of olive oil, which has a fluorescence-to-Raman signal ratio of 33 and a fluorescence lifetime of 2.5 ns, were distinguished at a distance of 30 cm with a 250 lux background illumination intensity. We believe that this kind of time-correlated CMOS single-photon avalanche diode sensor could pave the way for new compact distance-resolving Raman radars for application where distance information within a range of several metres is needed at the same time as a Raman spectrum.
作者: Jere Kekkonen,Jan Nissinen,Juha Kostamovaara,Ilkka Nissinen
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To present a distance-resolving Raman radar device based on a time-correlated CMOS single-photon avalanche diode line sensor that can measure the location of the target sample simultaneously with the normal stand-off spectrometer operation and suppress the background radiation dramatically by means of sub-nanosecond time gating.

The technology concerned enables distance scanning with 3.75 cm resolution in order to derive the distance from the Raman sample simultaneously with the Raman spectrum. The CMOS technology makes it possible to integrate optical detectors and all the other electronics into the same die and, thus, sub-nanosecond gating can be achieved more conveniently than with traditional time-gated CCDs or ICCDs, in which gating of several nanoseconds is normally used. This allows us to further reduce the background noise and the fluorescence of the sample that has a nanosecond-scale lifetime. We believe that this technology could pave the way for a new kind of distance-resolving Raman radar device for applications in mining and explosive detection, where a compact stand-off device with a distance range of several metres is needed.

The optics and SPAD sensor circuit of the Raman radar were originally optimized for measurements through the microscope objective with the same excitation and collection axis, the objective of the microscope were simply removed and the measurements were performed at what was optically a relatively poor performance level. In addition, the off-chip delay unit was needed here because cm-level gate position sweeping of this kind had not been needed in the previously designed Raman microscope.

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