研究目的
Design and Development of a novel lanthanum inserted CuCr2O4 nanoparticles photocatalyst for the efficient removal of water pollutions.
研究成果
In summary, insertion of lanthanum in the CuCr2O4 crystal structure have been demonstrated via a facile preparation route. Among the various prepared La doped samples CuCrLaO4 demonstrated the highest activity for the degradation of water pollutions. According to the trapping tests the.O2- was the major reactive kinds for the degradation of RhB and MO under incident illumination. Based on the obtained results, the remarkable enhanced photocatalytic ability of the lanthanum inserted structure can be related to the development of more charge carrier species, and lower recombination of electron-hole pairs in the photocatalyst. Additionally, according to the reusability experiments the catalyst can be reused five times without remarkable loss in the photocatalytic activity.
研究不足
The study does not mention any specific limitations or areas for optimization.
1:Experimental Design and Method Selection:
The insertion of lanthanum in the CuCr2O4 lattice structure was performed via a simple preparation approach using the Pechini Sol-gel method. Different loading percentages of lanthanum in the CuCr2O4 crystal structure were successfully performed.
2:Sample Selection and Data Sources:
Chemical precursors including copper nitrate trihydrate, chromium nitrate nonahydrate, lanthanum nitrate, citric acid, distilled water, sodium hydroxide, and ammonia were used as starting materials.
3:List of Experimental Equipment and Materials:
Characterization methods included x-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), Diffuse reflectance (DRS), and Vibrating Sample Magnometer (VSM).
4:Experimental Procedures and Operational Workflow:
The photocatalytic activity was evaluated for the destruction of RhB and MO organic contaminants under incident visible light illumination using a LED lamp (λ= 440 nm).
5:Data Analysis Methods:
The photocatalytic degradation efficiency was analyzed using UV-Vis Spectrophotometer.
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