研究目的
Investigating the combination of ternary metal oxides effect on elemental mercury (Hg0) removal.
研究成果
The MnOx-FeOx-CrOx/TiO2 catalyst demonstrated superior Hg0 removal efficiency at low temperatures due to the uniform dispersion of metal oxide nanoparticles, high Mn4+ concentration, and surface adsorbed oxygen species. The catalyst's performance was enhanced by the presence of O2 and NO, while NH3 had an inhibitive effect.
研究不足
The study focuses on low-temperature Hg0 removal and does not extensively explore the effects of higher temperatures or other flue gas components beyond O2, NO, and NH3.
1:Experimental Design and Method Selection
TiO2 nanorods-supported MnOx, FeOx, CrOx, and MnOx-FeOx-CrOx catalysts were prepared by a deposition-precipitation method to investigate their effect on Hg0 removal.
2:Sample Selection and Data Sources
TiO2 nanorods were synthesized through a hydrothermal method. Metal oxide catalysts were prepared by dispersing metal nitrate precursors on TiO2 nanorods.
3:List of Experimental Equipment and Materials
Field-emission scanning electron microscope (Verios 460L, Thermo Fischer Scientific), transmission electron microscopy (TEM: JEM-1010, JEOL), high-resolution transmission electron microscopy (HR-TEM: JEOL 2100F), X-ray diffractometer (D8 Advance, Bruker), N2-BET specific surface area analyzer (ASAP 2400, Micromeritics), X-ray photoelectron spectroscopy (K-Alpha, Thermo Fischer Scientific).
4:Experimental Procedures and Operational Workflow
Catalysts were characterized by SEM, TEM, HRTEM, XRD, BET surface area, and XPS. Hg0 removal efficiency was tested in a bench-scale experimental setup.
5:Data Analysis Methods
Hg0 removal efficiency was calculated based on the quantification of outlet oxidized mercury and captured elemental mercury using cold-vapor atomic fluorescence spectroscopy (CV-AFS).
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X-ray diffractometer
D8 Advance
Bruker
Crystallographic examination of catalysts
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X-ray photoelectron spectroscopy
K-Alpha
Thermo Fischer Scientific
Surface analysis of catalysts
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Field-emission scanning electron microscope
Verios 460L
Thermo Fischer Scientific
Identification of nanostructure dimensions
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Transmission electron microscopy
JEM-1010
JEOL
Study of sample morphologies
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High-resolution transmission electron microscopy
JEOL 2100F
JEOL
Evaluation of exposed crystal planes and their corresponding lattice spacings
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N2-BET specific surface area analyzer
ASAP 2400
Micromeritics
Determination of specific surface area
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Hg0 vapor generator
Model 150 Dynacalibrator
VICI Metronics
Production of inlet mercury concentration
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Cold-vapor atomic fluorescence spectroscopy
Millennium Merlin
PS Analytical
Quantification of outlet oxidized mercury and captured elemental mercury
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