研究目的
Investigating the fabrication of durable, optically transparent, superhydrophobic polymer films for optical applications exposed to flowing water.
研究成果
The study successfully fabricated durable, optically transparent, superhydrophobic free-standing polymer films using a simple lamination method. The films exhibited excellent superhydrophobicity, high transparency, and durability under flowing water, making them suitable for optical applications exposed to water.
研究不足
The study focuses on the durability under flowing water and optical transparency but does not extensively cover mechanical abrasion resistance or the effects of environmental factors other than water flow.
1:Experimental Design and Method Selection:
A lamination approach was used to treat free-standing films to become superhydrophobic by partially embedding hydrophobic silica nanoparticles into the surface of a cyclic olefin polymer (COP) film.
2:Sample Selection and Data Sources:
Cyclic olefin polymer film (Cyclo Olefin Polymer ZF16) and hydrophobic silica nanoparticles (AEROSIL R202 and AEROSIL R812S) were used.
3:List of Experimental Equipment and Materials:
COP film, hydrophobic silica nanoparticles, isopropanol, dip-coating instrument, glass plates, Perkin Elmer Lambda 650 spectrophotometer, AMRAY 1910 Field Emission Scanning Electron Microscope (FESEM), TA Instruments model Q100 DSC, TA Instruments model Q500 TGA, goniometer (model 250-F1, ramé-hart Instrument Co), Omicron Nanotechnology system (EA-125) XPS.
4:Experimental Procedures and Operational Workflow:
Silica nanoparticles were deposited onto the polymer film using a dip-coating method; the nanoparticles were subsequently partially embedded into the surface of the film by thermal lamination.
5:Data Analysis Methods:
UV-Vis spectra, SEM, DSC, TGA, contact angle and sliding angle measurements, XPS.
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Perkin Elmer Lambda 650 spectrophotometer
Lambda 650
Perkin Elmer
Used to acquire direct transmittance spectra of the prepared SH films.
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Cyclo Olefin Polymer ZF16
ZF16
Zeonex
Used as the substrate for the superhydrophobic films.
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AEROSIL R202
R202
Evonik
Hydrophobic silica nanoparticles used to create surface roughness for superhydrophobicity.
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AEROSIL R812S
R812S
Evonik
Hydrophobic silica nanoparticles used to create surface roughness for superhydrophobicity.
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AMRAY 1910 Field Emission Scanning Electron Microscope
1910
AMRAY
Used to characterize the surface morphology of the films.
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TA Instruments model Q100 DSC
Q100
TA Instruments
Used to measure thermal properties of the COP film.
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TA Instruments model Q500 TGA
Q500
TA Instruments
Used to perform thermogravimetric analysis on the samples.
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ramé-hart Instrument Co goniometer
250-F1
ramé-hart Instrument Co
Used to measure the static contact angle and tilt angle at which droplets slide off the surface.
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Omicron Nanotechnology system (EA-125) XPS
EA-125
Omicron Nanotechnology
Used to study the chemical composition of the surfaces before and after water tunnel tests.
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