研究目的
To propose a feasible and accurate method for calculating the main radiative properties of soot particle ensembles in flames except scattering matrix and depolarization ratio.
研究成果
The proposed method effectively avoids the huge trouble of the exact geometric structure reconstruction and direct radiative property calculation of all soot particles in an ensemble. The impacts of particle structure and incident wavelength on the radiative properties of soot particle ensembles should not be ignored, especially for ones containing many large isolated soot primary particles or fractal soot aggregates.
研究不足
The method does not calculate the scattering matrix and depolarization ratio of soot particle ensembles. The exact geometric structure reconstruction of all soot particles in an ensemble is practically impossible due to their enormous number.
1:Experimental Design and Method Selection:
The study uses the tunable dimension cluster-cluster aggregation (TDCCA) model to generate fractal aggregates with prescribed values of Df and kf. The discrete dipole approximation (DDA) method is employed to calculate absorption and scattering of electromagnetic waves by targets with arbitrary geometries.
2:Sample Selection and Data Sources:
Soot particles were extracted from an ethylene diffusion flame using a thermophoretic sampling probe and examined by a TEM.
3:List of Experimental Equipment and Materials:
A Santoro-style burner, mass flow controllers, TEM grids, a TEM (FEI, Tecnai G2), and software packages DDSCAT 7.3.2 and MSTM 3.
4:2 and MSTM Experimental Procedures and Operational Workflow:
0.
4. Experimental Procedures and Operational Workflow: Soot particles were captured by TEM grids mounted on a metal clip driven into the flame. TEM images were analyzed to obtain structural parameters. The radiative properties were calculated using the TDCCA model and DDA method.
5:Data Analysis Methods:
The spline interpolation method was used to calculate the radiative properties of isolated soot primary particles. The coefficients of variation were used to assess the dispersion of the volume and radiative properties of equivalent soot particles.
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