研究目的
To prepare polymeric nanocomposites with enhanced dielectric, electromechanical and hydrophobic performance by introducing the core-shell AgNWs@SiO2 filler into polydimethylsiloxane (PDMS).
研究成果
The homogenous core-shell AgNWs@SiO2 effectively enhances the dielectric, electromechanical, and hydrophobic properties of PDMS nanocomposites. The nanocomposites show great potential for applications in dielectric elastomer materials and electrowetting devices.
研究不足
The study focuses on the enhancement of dielectric, electromechanical, and hydrophobic properties of PDMS nanocomposites with AgNWs@SiO2 filler. The limitations include the specific focus on AgNWs@SiO2 filler and PDMS matrix, which may not be directly applicable to other polymer matrices or filler types.
1:Experimental Design and Method Selection:
A two-step sol-gel process was used to synthesize homogenous core-shell AgNWs@SiO2. The nanocomposites were prepared by introducing AgNWs@SiO2 into PDMS matrix.
2:The nanocomposites were prepared by introducing AgNWs@SiO2 into PDMS matrix. Sample Selection and Data Sources:
2. Sample Selection and Data Sources: Silver nanowires (AgNWs) were prepared through a polyol method. Core-shell nanostructure of silica-coated AgNWs (AgNWs@SiO2) was synthesized through a flexible sol-gel approach.
3:List of Experimental Equipment and Materials:
Field emission scanning electron microscopy (FESEM, SU-8010, Hitachi Ltd, Japan), transmission electron microscopy (TEM, HT-7700, Hitachi Ltd, Japan), X-ray diffraction (XRD, EMPYREAN, PANalytical Co., Netherlands), Fourier transform infrared spectrometer (FTIR, VERTEX-70, Bruker, Ettlingen, Germany), X-ray photoelectron spectrometer (XPS, Thermo ESCALAB 250XI, USA), thermogravimetric analysis (TGA, Q500, USA), differential scanning calorimetry (DSC, NETZSCH DSC 204 HP, Germany), 4294 A Precision Impedance Analyzer (Agilent), OCA20 (Dataphysics, Germany), atomic force microscope (AFM, MultiMode, VEECO, USA), universal test machine (UTM2503, Suns, Shenzhen), dynamic mechanical analysis (DMA Q800, USA).
4:Experimental Procedures and Operational Workflow:
AgNWs were synthesized and then coated with SiO2 through a sol-gel approach. The AgNWs@SiO2/PDMS nanocomposites were prepared by solution blending and casting approach. The dielectric, hydrophobic, and mechanical properties of the nanocomposites were characterized.
5:Data Analysis Methods:
The dielectric properties were analyzed using a Precision Impedance Analyzer. The hydrophobic properties were measured by static contact angle measurements. The mechanical properties were tested using a universal test machine and dynamic mechanical analysis.
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Transmission electron microscopy
HT-7700
Hitachi Ltd
Characterization of the structure of inorganic fillers
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X-ray diffraction
EMPYREAN
PANalytical Co.
Characterization of the structure of inorganic fillers
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Fourier transform infrared spectrometer
VERTEX-70
Bruker
Identification of the chemical composition of the filler
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X-ray photoelectron spectrometer
Thermo ESCALAB 250XI
Thermo
Identification of the chemical composition of the filler
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Precision Impedance Analyzer
4294 A
Agilent
Measurement of dielectric properties
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Atomic force microscope
MultiMode
VEECO
Observation of surface structure and roughness
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Field emission scanning electron microscopy
SU-8010
Hitachi Ltd
Observation of morphology and structure of inorganic fillers and the freeze-fractured cross-section morphology of the films
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Thermogravimetric analysis
Q500
USA
Thermal stability analysis
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Differential scanning calorimetry
NETZSCH DSC 204 HP
Germany
Measurement of glass-transition temperature
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Static contact angle measurements
OCA20
Dataphysics
Measurement of static contact angle
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Universal test machine
UTM2503
Suns
Measurement of tensile stress and strain
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Dynamic mechanical analysis
DMA Q800
USA
Measurement of storage and loss modulus
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