研究目的
To increase the adhesion strength between PTFE and an Ag metal film formed from Ag ink using open-air plasma treatment at atmospheric pressure.
研究成果
The addition of H2 to Ar plasma was effective in preventing coloration and improving the adhesion strength of Ag/PTFE, achieving high adhesion strength even after prolonged plasma treatment. The uniformity of treatment with Ar + H2 plasma was superior to that with Ar plasma, making it suitable for industrial applications.
研究不足
The study focused on PTFE and may not be directly applicable to other fluoropolymers without further research. The optimal conditions for H2 addition need to be carefully controlled to achieve the desired adhesion strength.
1:Experimental Design and Method Selection:
The study involved open-air plasma treatment of PTFE at atmospheric pressure using Ar, Ar + O2, and Ar + H2 gases to modify the PTFE surface for improved adhesion with Ag ink.
2:Sample Selection and Data Sources:
PTFE sheets were used as samples, cleaned with acetone and pure water, and dried before plasma treatment.
3:List of Experimental Equipment and Materials:
Equipment included an open-air plasma treatment system, multichannel spectrometer, spin coater, ceramic heater, peel tester, and various analytical instruments like XPS, AFM, ESR, and water contact angle tester.
4:Experimental Procedures and Operational Workflow:
The process included plasma irradiation, exposure to air, coating with Ag ink, and heating to form an Ag film. Adhesion strength was measured using a peel test.
5:Data Analysis Methods:
Data were analyzed using XPS for chemical composition, AFM for surface morphology, ESR for radical density, and water contact angle measurements for wettability.
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multichannel spectrometer
HR-4000CG-UV-NIR
Ocean Optics
Recording optical emission spectra during plasma treatment
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atomic force microscopy
SPM-9700
Shimadzu
Observing the morphology of the PTFE surfaces
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electron spin resonance spectrometer
JES-FA100
JEOL
Characterizing peroxy radicals formed on the plasma-treated PTFE surface
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spin coater
1H-D7
Mikasa
Coating the PTFE surface with Ag ink uniformly
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ceramic heater
HHP-170D
AS-ONE
Heating the PTFE samples coated with Ag ink
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peel tester
ZP-200
IMADA
Measuring the adhesion strength between Ag ink films and PTFE samples
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water contact angle tester
Drop Master 300
Kyowa Interface Science
Measuring the static contact angle to determine the wettability of PTFE surfaces
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