研究目的
Understanding the variation of KDP crystal surface height by a rapid growth technique and the effects of various parameters on growth rate fluctuation.
研究成果
The growth rate on KDP crystal surfaces is uniform at the macroscale but fluctuates at the microscale, leading to protrusions and depressions. Controlling supersaturation, paddle’s rotational speed, and impurity concentration can reduce inclusions and improve crystal quality.
研究不足
The study focuses on numerical simulations and theoretical models, which may not fully capture all real-world complexities of KDP crystal growth. Experimental validation is limited to surface characteristics measurement.
1:Experimental Design and Method Selection:
Numerical simulations coupling macroscopic transport of solute and impurities with microscopic interfacial kinetics processes.
2:Sample Selection and Data Sources:
KDP crystal growth under varying conditions of crystal size, bulk supersaturation, rotation rate of the stirring paddle, and impurities.
3:List of Experimental Equipment and Materials:
KDP growth crystallizer consisting of a plate, a frame, and two stirring paddles.
4:Experimental Procedures and Operational Workflow:
Simulations performed under component and hydrodynamic equilibrium for constant distributions of slope on each vicinal sector, with bulk supersaturation remaining unchanged during growth.
5:Data Analysis Methods:
Analysis of surface supersaturation and slope distributions, growth rate fluctuations, and their effects on crystal quality.
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