研究目的
To apply MnO2 immobilized in amberlite matrix to degrade Alizarin red S under UV illumination.
研究成果
The study successfully demonstrated the fabrication of MnO2-amberlite and its application in the photocatalytic degradation of Alizarin red S under UV light. The 18 h-stirring time was found to be optimal for the largest surface area and effective degradation. Despite the low degradation percentage, the method shows promise for future applications with modifications.
研究不足
The percentage of Alizarin red S degradation is still low, indicating potential areas for optimization in the fabrication process and photocatalytic conditions.
1:Experimental Design and Method Selection:
The study involved the synthesis of MnO2-amberlite through stirring at different times (6, 12, 18, 24, and 30 h) and its characterization using BET, FTIR, XRD, and SEM. The photocatalytic degradation of Alizarin red S was examined under UV light.
2:Sample Selection and Data Sources:
Alizarin red S was used as the model compound for degradation. MnO2 and amberlite IRA 400 (Cl) were used for the synthesis of MnO2-amberlite.
3:List of Experimental Equipment and Materials:
Equipment included a magnetic stirrer, oven, furnace, centrifuge, UV-visible spectrophotometer, FTIR spectrometer, XRD diffractometer, and SEM. Materials included MnO2, amberlite IRA 400 (Cl), and Alizarin red S.
4:Experimental Procedures and Operational Workflow:
The synthesis involved grinding amberlite, dissolving it in water, adding MnO2, stirring at different times, centrifuging, drying, and calcination. The photocatalytic degradation was carried out under UV light, and the degradation percentage was calculated.
5:Data Analysis Methods:
The degradation percentage was calculated using the formula provided. BET analysis was used to compute specific surface areas, and FTIR, XRD, and SEM were used for characterization.
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Siemens D5000 X-ray diffractometer
D5000
Siemens
Used for XRD analysis
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UV-visible spectrophotometer
Lambda 25
Perkin Elmer
Used to examine the degradation percentage of Alizarin red S
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MnO2
Merck Schuchardt OHG
Used for synthesis of MnO2-amberlite
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amberlite IRA 400 (Cl)
Sigma Aldrich Chemi GmbH
Used for ion exchange resin
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Alizarin red S
Fluka Chemie AG
Model compound for degradation
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micrometrics PulseChemiSorb 2705
2705
micrometrics
Used for BET analysis
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Perkin Elmer instrument
Perkin Elmer
Used for FTIR characterization
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Philips XL 40 Holland instrument
XL 40
Philips
Used for SEM imaging
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gold sputter coater
Polaron Divisio System SEM coating Bio-Rad
Used to coat material powder before running SEM
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