研究目的
Developing novel form-stable composite phase change materials (FS-CPCM) for solar energy conversion and storage, focusing on enhancing thermal conductivity and light-to-heat conversion efficiency.
研究成果
The LA/LA-GA FS-CPCMs exhibit enhanced thermal conductivity, excellent phase change behavior, and high light-to-heat conversion efficiency, making them promising for solar energy storage applications. The materials show good thermal reliability and stability, with potential for further optimization and application in solar energy systems.
研究不足
The study focuses on the synthesis and characterization of FS-CPCMs but does not extensively explore long-term durability under real-world solar energy storage conditions or scalability of the synthesis process.
1:Experimental Design and Method Selection:
The study employed a vacuum impregnation method to prepare FS-CPCMs, with lauric acid (LA) as the phase change material (PCM) and graphene aerogel (GA) as the supporting material. LA was grafted onto GA through an esterification reaction and reduction process to enhance thermal conductivity.
2:Sample Selection and Data Sources:
LA and GA were used as primary materials, with specific ratios for composite preparation.
3:List of Experimental Equipment and Materials:
Materials included lauric acid, graphene oxide, and various chemical reagents. Equipment included SEM, FT-IR, Raman spectrometer, XRD, DSC, TGA, and thermal constants analyzer.
4:Experimental Procedures and Operational Workflow:
The process involved preparation of GO, esterification to graft LA onto GO, reduction to form LA-GA, and vacuum impregnation to prepare FS-CPCMs.
5:Data Analysis Methods:
Microstructure, thermal properties, and light-to-heat conversion efficiency were analyzed using SEM, FT-IR, Raman spectroscopy, XRD, DSC, TGA, and thermal conductivity measurements.
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Scanning electron microscope
Sigma 300
ZEISS Company
Surface morphology analysis
-
X-ray diffractometer
Smart Lab 3
RIGAKU
Crystalline structure characterization
-
Lauric acid
Chengdu Kelong Chemical Reagent Company
Phase change material for thermal energy storage
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Graphene oxide
Qingdao Jinrilai Graphit Co.
Supporting material for composite phase change materials
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Fourier transform infrared spectroscopy
Magna 750
Nicole Company
Functional groups characterization
-
Raman spectrometer
inVia
Renishaw
Raman spectra analysis
-
Differential scanning calorimeter
DSC 200 F3 Maia
NETZSCH
Phase change behavior analysis
-
Thermal gravimetric analyzer
Netzsch STA449 F3
Germany
Weight loss and thermal stability analysis
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Thermal constants analyzer
TPS2500S
Hot Disk
Thermal conductivity testing
-
Multichannel temperature recorder
TOPRIE-TP700
Bost
Heat storage and release properties testing
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Solar Simulator
Sun 2000
Abet Technologies
Simulated sunlight for photo-to-heat conversion test
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Optical power meter
CEL-NP2000
Ceaulight
Light irradiation power verification
-
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