研究目的
Investigating the impact of using proximal derived measurements of soil total carbon taken at point locations on upscaling to landscape levels.
研究成果
Using proximal sampling and modelling provides comparable output to laboratory measured soil TC measurements at point level, but when upscaled to landscape level the selection of proximal modelling method will impact the spatial interpolations derived. The error propagation within sequential modelling must be considered particularly when one wishes to use sequential modelling to analyse change in environmental properties.
研究不足
The study highlights the challenges of upscaling point-based measurements to landscape levels, including error propagation within sequential modelling. The complexity of the Florida, USA landscape and the under-prediction in the higher range of logTC values are noted limitations.
1:Experimental Design and Method Selection:
The study involved collecting 1087 soil samples across Florida, USA, analyzing them in the laboratory for total carbon (TC), and measuring them using visible-/near-infrared (VNIR) spectroscopy. Proximal TC values were generated through chemometric modelling using random forest (RF) and partial least squares (PLS) regression. These datasets were then upscaled to the State of Florida, USA using ordinary kriging and compared.
2:Sample Selection and Data Sources:
Soil samples were collected using a stratified random sampling design across Florida, USA.
3:List of Experimental Equipment and Materials:
Laboratory analysis for TC was performed using a Shimadzu TOC-Vcpn catalytic combustion oxidation instrument. VNIR diffuse reflectance spectra (DRS) were acquired with an Analytical Spectral Devices Lab Spec
4:Experimental Procedures and Operational Workflow:
50 Soil samples were air-dried, sieved, and analyzed for TC. Spectral data acquisition involved scanning samples from above at four positions using a custom designed rotating sample stage.
5:Data Analysis Methods:
Chemometric modelling techniques (PLS and RF) were applied to model and predict soil TC. Geospatial modelling was conducted using ordinary kriging.
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