研究目的
To study the protective properties of a poly(alkyl siloxane) coating enriched with photoactive nano-ZnO on glauconitic sandstone, focusing on visual appearance, hydrophobicity, porosity, water absorption/evaporation, and self-cleaning ability.
研究成果
The nano-ZnO/poly(alkyl siloxane) coating significantly enhances hydrophobicity (contact angle 128°) and provides self-cleaning properties under UV irradiation, with over 50% reduction in water absorption for up to 8 hours. Although it shortens the protection time compared to pure Porosil, the added benefits make it a promising candidate for protecting sandstone monuments, with recommendations for future studies on optimizing the coating composition.
研究不足
The exact chemical composition of Porosil is not disclosed, limiting predictability. The coating partially blocks pores but does not prevent long-term water absorption. The reduction in water absorption time for ZnO-enriched coating is shorter compared to pure Porosil, and further research is needed to address this issue.
1:Experimental Design and Method Selection:
The study involved applying poly(alkyl siloxane) coatings with and without 0.5 wt% nano-ZnO to sandstone samples, comparing them with uncoated sandstone. Methods included colorimetry, X-ray diffraction, SEM, mercury intrusion porosimetry, contact angle measurements, water absorption/evaporation tests, and photocatalytic activity assessments using methylene blue degradation under UV irradiation.
2:5 wt% nano-ZnO to sandstone samples, comparing them with uncoated sandstone. Methods included colorimetry, X-ray diffraction, SEM, mercury intrusion porosimetry, contact angle measurements, water absorption/evaporation tests, and photocatalytic activity assessments using methylene blue degradation under UV irradiation. Sample Selection and Data Sources:
2. Sample Selection and Data Sources: Green glauconitic sandstone specimens were cut into various sizes (e.g., 50x100x150 mm, 10x10x20 mm, 10x50x100 mm) from quarry blocks, selected based on bulk density similarity. ZnO nanoparticles were synthesized hydrothermally.
3:List of Experimental Equipment and Materials:
Equipment included Bruker D8 Advance diffractometer, Hitachi SU6600 SEM, AutoPore 9500 porosimeter, CINTRA 303 UV-VIS spectrophotometer, MiniScan EZ 4500S spectrophotometer, air brush Fengda BD-182, compressor Fengda AS18-2. Materials included zinc chloride, sodium hydroxide, methylene blue, poly(alkyl siloxane) Porosil VV plus.
4:Materials included zinc chloride, sodium hydroxide, methylene blue, poly(alkyl siloxane) Porosil VV plus. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Coatings were applied by spraying in three layers. Samples were analyzed for phase composition, surface morphology, pore distribution, hydrophobicity (via contact angle), water absorption/evaporation dynamics, and photocatalytic activity (using methylene blue degradation and colorimetry).
5:Data Analysis Methods:
Data were analyzed using ImageJ for contact angles, linear regression for absorption curves, and statistical methods for standard deviations. Color differences were calculated using DE* formula.
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scanning electron microscope
SU6600
Hitachi Ltd.
Used to observe surface morphology of samples and perform energy dispersive X-ray spectroscopy.
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diffractometer
D8 Advance
Bruker AXS
Used for X-ray powder diffraction analysis to study phase composition of samples.
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porosimeter
AutoPore 9500
Micromeritics
Used for mercury intrusion porosimetry to assess pore size distribution.
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spectrophotometer
CINTRA 303
GBC Scientific Equipment
Used for UV-VIS spectroscopy to determine band gap energy and measure photocatalytic degradation.
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spectrophotometer
MiniScan EZ 4500S
HunterLab
Used for colorimetric measurements to quantify color changes in samples.
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air brush
BD-182
Fengda
Used for spraying the coatings onto sandstone specimens.
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compressor
AS18-2
Fengda
Used with the air brush for spraying applications.
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optical polarizing microscope
Eclipse 80i
Nikon Corp.
Used for petrographic analysis of thin sections to determine mineral composition.
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UV lamp
LT 36 W/073 Blacklight blue
Narva
Used as a UV light source for photocatalytic experiments.
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