研究目的
To synthesize Ag-ZnO nanocomposites with different Ag concentrations for enhanced photocatalytic degradation of methylene blue under UV light irradiation.
研究成果
Ag-ZnO nanocomposites, especially with 6% Ag concentration, show enhanced photocatalytic degradation of methylene blue under UV light due to improved charge separation and reduced electron-hole recombination. This provides a simple and effective method for potential wastewater treatment applications.
研究不足
The study is limited to UV light irradiation; performance under visible light or other conditions is not extensively evaluated. The scalability and real-world application in wastewater treatment may require further optimization.
1:Experimental Design and Method Selection:
The study involved synthesizing ZnO nanorods via hydrothermal treatment and Ag nanoparticles via chemical reduction, then decorating ZnO with Ag nanoparticles at various concentrations (1-10%) to form nanocomposites. The photocatalytic performance was evaluated under UV light.
2:Sample Selection and Data Sources:
Methylene blue (MB) was used as the model dye. All reagents were analytical grade, purchased from Sigma-Aldrich and Daejung Chemicals.
3:List of Experimental Equipment and Materials:
Equipment included SEM (JEOL JSM-7500F), DLS (DynaPro NanoStar, Wyatt), Bio-AFM (NanoWizard II; JPK), XRD (Scintag-SDS 2000), UV-Vis spectroscopy (Alpha-1106), PL spectroscopy (Malvern Instruments), FT-IR (Nicolet 6700). Materials included AgNO3, NaBH4, NaOH, sodium citrate, CTAB, zinc acetate, ammonia solution, methanol, ethanol, and Milli-Q water.
4:0). Materials included AgNO3, NaBH4, NaOH, sodium citrate, CTAB, zinc acetate, ammonia solution, methanol, ethanol, and Milli-Q water. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: ZnO NRs were synthesized hydrothermally, Ag NPs were synthesized chemically, and nanocomposites were formed by mixing ZnO with Ag NPs in CTAB solution. Photocatalysis tests involved dissolving samples in MB solution, irradiating with UV light (365 nm), and measuring UV-Vis spectra at intervals.
5:Data Analysis Methods:
Data were analyzed using UV-Vis and PL spectroscopy to measure degradation rates and photocatalytic properties.
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Scanning Electron Microscope
JSM-7500F
JEOL
Examining the morphologies of the samples
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Dynamic Light Scattering
DynaPro NanoStar
Wyatt
Measuring the sizes of the particles
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Atomic Force Microscope
NanoWizard II
JPK
Measuring the sizes of the particles in intermittent air mode
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X-ray Diffractometer
Scintag-SDS 2000
Analyzing the crystalline structures of the samples
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UV-Visible Spectrophotometer
Alpha-1106
Determining the chemical properties of the samples
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Photoluminescence Spectrometer
Malvern Instruments
Determining the chemical properties of the samples
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Fourier Transform Infrared Spectrometer
Nicolet 6700
Determining the chemical properties of the samples
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