研究目的
To investigate the corrosion behavior of pulsed Nd:YAG laser cladded Ti-6Al-4V alloy in NaCl, HCl and H2SO4 solutions.
研究成果
Laser cladding improved the corrosion resistance of Ti-6Al-4V alloy in NaCl and H2SO4 solutions, with higher laser powers enhancing performance due to homogeneous microstructure formation. However, in HCl solution, high laser powers led to worse corrosion resistance due to cavity formation. The coatings exhibited good metallurgical bonding and a dual-phase structure (α and α' martensite), contributing to the observed behaviors. Future studies could focus on optimizing laser parameters to reduce defects and expand to other corrosive media.
研究不足
The study is limited to specific laser parameters and corrosive environments; results may not generalize to other conditions. Presence of cavities at high laser powers could affect corrosion resistance, particularly in HCl, indicating potential optimization needs in process parameters to minimize defects.
1:Experimental Design and Method Selection:
Laser cladding was performed using a pulsed Nd:YAG laser at different laser powers (150 W, 200 W, 250 W) with fixed scanning speed (2 mm/s), powder feeding rate (500 mg/s), and other parameters. Microstructural analysis was conducted using FE-SEM and XRD. Corrosion behavior was assessed via potentiodynamic polarization tests in 3.5% NaCl, 2% H2SO4, and 5% HCl solutions following ASTM-G61 standard.
2:5% NaCl, 2% H2SO4, and 5% HCl solutions following ASTM-G61 standard.
Sample Selection and Data Sources:
2. Sample Selection and Data Sources: Ti-6Al-4V alloy was used as both substrate and cladding powder, with chemical composition verified by arc spark optical emission spectrometry. Powder morphology and size (90–125 μm) were characterized.
3:List of Experimental Equipment and Materials:
Equipment included a pulsed Nd:YAG laser device, FE-SEM (MIRA3 LMU, TESCAN), X-ray diffractometer (MPD-Xpert, Philips), and potentiostat (EG&G 273A). Materials included Ti-6Al-4V powder (Advanced Powders and Coatings Inc.), argon gas, Kroll's reagent for etching, and corrosive solutions (NaCl, H2SO4, HCl).
4:Experimental Procedures and Operational Workflow:
Laser cladding was performed with argon shielding and carrier gas. Samples were metallographically prepared, etched, and analyzed for microstructure and phases. Polarization tests started with OCP stabilization for 1000 s, scanning from -100 to +450 mV vs. OCP at 1 mV/s using a three-electrode setup (SCE reference, platinum auxiliary, working electrode with 2 cm2 area).
5:Data Analysis Methods:
Microstructural images and XRD patterns were analyzed to identify phases. Polarization curves were used to determine corrosion potential and current density, with comparisons made between samples and untreated alloy.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容