研究目的
To assess defects in large-area graphene electrodes using infrared imaging of Joule heat emission to estimate uniformity and mechanical continuity.
研究成果
Infrared imaging is a useful, fast, and non-destructive method for diagnosing graphene electrode imperfections, providing micrometric resolution and applicability to both large-area and microscopic layers. It identifies thermal signatures of defects and resistivity inhomogeneities, with simulations confirming observed heat distributions.
研究不足
Resolution depends on wavelength, optics, detector pixels, and temperature dissipation; substrate temperature limited to about 200°C to prevent cracking; unable to detect temperature changes from multilayer graphene islands due to limited IR optics resolution.
1:Experimental Design and Method Selection:
The method involves infrared imaging of Joule-heated graphene under electric current flow to visualize temperature non-uniformity caused by defects. Finite element method simulations were used to model Joule heating distribution.
2:Sample Selection and Data Sources:
Graphene monolayer grown on copper foil by CVD and transferred onto glass substrates of various sizes (25 mm × 25 mm to 40 mm × 100 mm, thickness 0.7–2.5 mm) with metallic contacts on opposite edges.
3:7–5 mm) with metallic contacts on opposite edges. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: SEM Carl Zeiss Auriga cross beam workstation for surface quality verification; InSb 640 M camera (Thermosensorik/DCG Systems) with 1.1–4.9 μm detection range and optical filters, equipped with wide-field and microscopic lenses; FLIR T630sc camera with microbolometer detector (7.5–14 μm range); Peltier elements or heat sinks for cooling; glass substrates; DC power supply for polarization up to 200 V.
4:1–9 μm detection range and optical filters, equipped with wide-field and microscopic lenses; FLIR T630sc camera with microbolometer detector (5–14 μm range); Peltier elements or heat sinks for cooling; glass substrates; DC power supply for polarization up to 200 V. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Samples were DC polarized at various voltages; thermal images were recorded from the graphene side with and without cooling; temperature calibration using controlled temperature sample holder; differential imaging by subtracting reference images; intentional scratches made using ball-on-plane wear test.
5:Data Analysis Methods:
Finite element simulations using NETGEN 5.1 for mesh generation and ELMER FEM software for solving Maxwell's equations; thermal image analysis to identify hot spots and temperature profiles.
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SEM
Auriga cross beam workstation
Carl Zeiss
Verification of graphene surface quality
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IR camera
T630sc
FLIR
Infrared imaging with microbolometer detector
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IR camera
InSb 640 M
Thermosensorik/DCG Systems
Infrared imaging with detection wavelength range of 1.1–4.9 μm, equipped with wide-field and microscopic lenses
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Peltier element
Cooling of samples during measurements
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Heat sink
Cooling of samples during measurements
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DC power supply
Polarization of graphene samples up to 200 V
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