研究目的
To develop a membrane distillation device (MDD) using a carbon nanotube membrane, qualitative filter paper, and aerogel blanket for efficient solar harvesting and heat localization to enhance water evaporation, addressing freshwater shortage through seawater desalination.
研究成果
The MDD demonstrated efficient solar harvesting and heat localization, achieving a high thermal conversion efficiency of up to 84.6% and excellent cyclic stability over 10 cycles, making it a promising candidate for seawater desalination applications.
研究不足
The study may have limitations in scalability for industrial applications, potential agglomeration of CNTs at higher concentrations, and increased heat loss under higher light intensities due to air disturbance and thermal conduction/radiation.
1:Experimental Design and Method Selection:
The study designed a membrane distillation device (MDD) with a CNT membrane for solar absorption, a qualitative filter paper for water transmission, and an aerogel blanket for thermal insulation to achieve heat localization and efficient solar steam generation. The non-solvent-induced phase inversion method was used to prepare the CNT membrane.
2:Sample Selection and Data Sources:
Carboxyl multi-wall CNTs, PVDF, DMF, qualitative filter paper, and aerogel blanket were sourced from specified suppliers. Deionized water was used in experiments.
3:List of Experimental Equipment and Materials:
Spin coater (AC200-SE, Jiatu, China), SEM (Quanta 250FEG, FEI, USA), UV-Vis-NIR spectrometer (Cary 5000, Agilent, USA), FT-IR spectrometer (Nicolet iS50, Thermo Scientific, USA), high-speed camera (Mikrotron, Germany), thermal imager (TI100, Fluke, USA), xenon lamp (CEL-HXF300, Ceaulight, China), optical power meter (CEL-NP2000, Ceaulight, China), electronic balance (JJ224BF, G&G, China), T-type thermocouples (TT-T-36-SLE, Omega, USA), data acquisition system (Model 34970A, Agilent, USA).
4:Experimental Procedures and Operational Workflow:
The CNT membrane was prepared by spin-coating and phase inversion. The MDD was assembled and exposed to simulated solar light in a PMMA vessel. Weight changes and temperatures were monitored over time to evaluate evaporation rate and thermal conversion efficiency.
5:Data Analysis Methods:
Evaporation rate and thermal conversion efficiency were calculated using specified equations. Data were analyzed to assess the effects of CNT concentration and light intensity, and cyclic stability was tested over 10 cycles.
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Scanning Electron Microscope
Quanta 250FEG
FEI
Used to characterize the morphology of the CNT membrane.
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UV-Vis-NIR Spectrometer
Cary 5000
Agilent
Used to measure the UV-Vis-NIR spectra of CNT membranes.
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Fourier Transform Infrared Spectrometer
Nicolet iS50
Thermo Scientific
Used to measure the FT-IR spectra of CNT membranes.
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Thermal Imager
TI100
Fluke
Used to capture the temperature distribution of CNT membrane.
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Data Acquisition System
Model 34970A
Agilent
Used to connect to thermocouples for data acquisition during the experiment.
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Spin Coater
AC200-SE
Jiatu
Used for spin-coating the CNT membrane during preparation.
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High Speed Camera
Mikrotron
Used to detect the dynamic contact angle of water droplet on CNT membrane.
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Xenon Lamp
CEL-HXF300
Ceaulight
Used to simulate solar light in the solar steam generation experiment.
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Optical Power Meter
CEL-NP2000
Ceaulight
Used to adjust the light intensity in the solar steam generation experiment.
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Electronic Balance
JJ224BF
G&G
Used to record the weight change during the solar steam generation process.
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T-type Thermocouple
TT-T-36-SLE
Omega
Used to monitor the water temperature at different heights in the cylindrical vessel.
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