研究目的
To simultaneously realize high permittivity and breakdown strength in polymer nanocomposites by introducing low-concentration conductive MXene nanosheets into barium titanate/polyvinylidene fluoride composites to enhance interface polarization.
研究成果
Ternary nanocomposites with low-concentration MXene significantly improved permittivity due to enhanced interface polarization while maintaining acceptable dielectric loss, conductivity, and breakdown strength. The composite with 8 wt% BT and 2 wt% MXene achieved a permittivity of 77, loss of 0.15 at 100 Hz, and breakdown strength of 220 MV/m, demonstrating potential for high-energy-density dielectric applications with scalable fabrication.
研究不足
The use of unfunctionalized fillers may limit further optimization of interface properties; the study is limited to low filler concentrations and specific materials (BT, MXene, PVDF), and scalability to industrial production was not fully addressed.
1:Experimental Design and Method Selection:
Solution cast method was employed to fabricate binary BT/PVDF and ternary BT/MXene/PVDF nanocomposite films. The design rationale was to use low-concentration fillers to avoid agglomeration and improve interface compatibility.
2:Sample Selection and Data Sources:
Barium titanate (BT) nanoparticles with average size of 100 nm, titanium carbide MXene nanosheets, and polyvinylidene fluoride (PVDF) were used as materials. Weight concentrations of BT were varied from 0 to 8 wt%, and MXene was fixed at 2 wt%.
3:List of Experimental Equipment and Materials:
Materials included BT powder (Aladdin), MXene powder (Shanghai Bohan Chemical Technology Co., Ltd.), PVDF powder (Solvay), and DMF solvent (Tianjin Chemical Reagent Co., Ltd.). Equipment included ultrasonicator, magnetic stirrer, oven, LCR meter (HP4284A, Agilent), auto voltage withstanding tester (RK2674B), ferroelectric analyzer (Premiere ??, Radiant), and coater (JEOL JFC-1600).
4:0). Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Fillers were dispersed in DMF via ultrasonication and stirring, mixed with PVDF solution, stirred for 20 h, cast on glass slides, dried at 70°C, annealed at 180°C for 8 h under reduced pressure, and gold electrodes were sputtered for measurements.
5:Data Analysis Methods:
Dielectric properties were measured using an LCR meter from 100 Hz to 1 MHz, breakdown strength was measured with a voltage tester, and data were analyzed for permittivity, loss, conductivity, and breakdown strength trends.
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LCR meter
HP4284A
Agilent
Measure dielectric and alternative current conductive properties at frequencies from 100 Hz to 1 MHz.
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Ferroelectric analyzer
Premiere ??
Radiant
Obtain mono-polar electric hysteresis loops under ac field.
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Auto fine coater
JEOL JFC-1600
JEOL
Produce gold nanolayer electrodes.
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NMR spectrometer
Advance III
Bruker
Conduct proton nuclear magnetic resonance measurements.
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XRD diffractometer
D/max 2400
Rigaku
Perform X-ray diffraction tests.
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FE-SEM
EVO18
ZEISS
Achieve field-emission scanning electron microscopy results.
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TEM
JEM-200CX
JEOL
Obtain transmission electron microscopy results.
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Auto voltage withstanding tester
RK2674B
Measure electric breakdown property.
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