1：Experimental Design and Method Selection:

The study used a vapor diffusion method to form BHJ microspheres from rra-PHT and PCBM mixtures, with electrochemical and photoconductivity measurements to assess properties.

2：Sample Selection and Data Sources:

Samples included microspheres and solution-cast films with varying weight ratios of rra-PHT and PCBM, prepared in CHCl3 and MeOH solvents.

3：List of Experimental Equipment and Materials:

Equipment included scanning electron microscopy (SEM), transmission electron microscopy (TEM), cyclic voltammetry (CV) setup with glassy carbon electrode, X-ray photoelectron spectroscopy (XPS), and flash-photolysis time-resolved microwave conductivity (FP-TRMC). Materials included rra-PHT, PCBM, CHCl3, MeOH, TBAPF6 electrolyte, and acetonitrile.

4：Experimental Procedures and Operational Workflow:

Microspheres were formed by slow diffusion of MeOH vapor into CHCl3 solutions, followed by characterization using SEM, TEM, CV, XPS, and FP-TRMC to measure electrochemical properties, carrier mobilities, and lifetimes.

5：Data Analysis Methods:

Data were analyzed using CV for charge quantification, XPS for energy level shifts, and FP-TRMC for conductivity and lifetime measurements, with statistical analysis of results.