研究目的
To investigate PdEr-silicide formation using a developed PdEr-alloy target and evaluate the contact resistivity reduction to n-Si(100) via dopant segregation process.
研究成果
PdEr-silicide formation using a developed PdEr target successfully reduced the Schottky barrier height for electrons to 0.43 eV and achieved a contact resistivity of 4.0x10?8 Ωcm2 to n-Si(100) via dopant segregation process, indicating potential for improved MOSFET performance.
研究不足
The study may have limitations in thermal stability and scalability for industrial applications. Optimization of CBKR pattern fabrication could further reduce contact resistivity.
1:Experimental Design and Method Selection:
The study used RF magnetron sputtering with a PdEr-alloy target for film deposition, followed by rapid thermal annealing (RTA) for silicidation. Schottky barrier diodes (SBD) and cross-bridge Kelvin resistor (CBKR) methods were employed to evaluate Schottky barrier height and contact resistivity.
2:Sample Selection and Data Sources:
n-Si(100) substrates with resistivity of 1-10 Ωcm were used. Samples were cleaned using H2SO4:H2O2 = 4:1 (SPM) and HF:H2O = 1:100 (DHF) processes.
3:List of Experimental Equipment and Materials:
Equipment includes RF magnetron sputtering system, RTA system, XRD for crystallinity analysis, and 4-probe measurement setup. Materials include PdEr-alloy target (Pd:Er = 3:2, φ: 3 inch), TiN encapsulating layer, and Al for electrodes.
4:Experimental Procedures and Operational Workflow:
A 20 nm PdEr layer was deposited by RF sputtering at room temperature, followed by in-situ deposition of a 10 nm TiN layer. Silicidation was performed via RTA at 500°C for 5 min in N2/4.9%H2 ambient, with selective etching to remove unreacted metals. For CBKR, P ion implantation was done before silicidation.
5:9%H2 ambient, with selective etching to remove unreacted metals. For CBKR, P ion implantation was done before silicidation. Data Analysis Methods:
5. Data Analysis Methods: Schottky barrier height was extracted from J-V characteristics using the Schottky emission model. Contact resistivity was evaluated from V-I measurements of CBKR patterns, with linear extrapolation to zero contact area.
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RF magnetron sputtering system
Deposition of PdEr-alloy and TiN layers
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Rapid thermal annealing system
RTA
Silicidation process
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X-ray diffraction equipment
XRD
Crystallinity observation
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4-probe measurement setup
Sheet resistance evaluation
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PdEr-alloy target
Pd:Er = 3:2, φ: 3 inch
Sputtering target for PdEr layer deposition
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TiN encapsulating layer
Encapsulation to prevent oxidation
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Al electrode
Back contact formation
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Cross-bridge Kelvin resistor
CBKR
Contact resistivity evaluation
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