研究目的
To examine an alternative approach for value addition in quartz export by producing semi-processed and processed industry-specific quartz raw material, focusing on the chemical compositions and trace element variations in Sri Lankan vein quartz deposits.
研究成果
Industry-specific quartz raw material can be produced through selective mining and quality control during mining, transportation, and processing, reducing impurities to meet high-tech application standards. Different quartz types are suitable for various industries, such as chemically reinforced glass or ceramics, based on trace element contents.
研究不足
The study is limited to specific deposits in Sri Lanka; advanced processing technologies are not fully available locally, and the focus is on physical separation methods rather than chemical purification. Generalizability to other regions may be constrained.
1:Experimental Design and Method Selection:
The study evaluated the chemical compositions of vein quartz from seven deposits and processing plant products, using inductively coupled plasma optical emission spectroscopy (ICP-OES) and atomic absorption spectroscopy (AAS) for trace element analysis. Critical steps in mining, transport, and processing were assessed with reference to Fe and other trace elements.
2:Sample Selection and Data Sources:
Samples were collected from seven vein quartz deposits in the Badulla district, Sri Lanka, including different quartz types (colorless, milky, smoky, rose) and associations (with mica and feldspar). Ten samples of each type were powdered and mixed for representativeness.
3:List of Experimental Equipment and Materials:
Equipment included a Frantz isodynamic magnetic separator, reflected microscopy (Zeiss Axio Scope A1), SEM (Carl Zeiss evo 18), AAS (Thermo-iCE3500), ICP-OES (Agilent 720), and standard reagents from Sigma-Aldrich and Fluka Analytical. Materials included hydrofluoric acid, nitric acid, and standard reference materials.
4:Experimental Procedures and Operational Workflow:
Procedures involved sampling from mines, manual chipping to remove iron stains, transport simulation, size reduction using crushers and pulverizers, magnetic separation, and chemical analysis. Steps included washing, drying, and quality control measures.
5:Data Analysis Methods:
Data were analyzed using calibration graphs from AAS and ICP-OES, with statistical techniques for trace element concentrations, supported by microscopy and SEM for mineralogical evaluation.
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Reflected microscopy
Zeiss Axio Scope A1
Zeiss
Used to investigate the mineralogy of samples.
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SEM
Carl Zeiss evo 18
Carl Zeiss
Used for analyzing surface features and chemical composition of quartz fractures.
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Atomic absorption spectrometer
Thermo-iCE3500
Thermo
Used for analysis of Fe, Al, Ca, Mg, Na, K abundances.
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ICP-OES
Agilent 720
Agilent
Used for determining concentrations of trace elements Cr, Mn, Ni, Pb, Cu.
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Hydrofluoric acid
40%
Sigma-Aldrich
Used as a reagent in chemical analysis.
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Nitric acid
69%
Sigma-Aldrich
Used as a reagent in chemical analysis.
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Frantz isodynamic magnetic separator
Frantz
Used for dry magnetic separation to evaluate Fe contamination due to machine wear and tear.
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Standard solutions
1000 μg ml?1 for Fe, Al, Ca, Mg, Na, K, Cr, Mn, Ni, Pb, Cu
Fluka Analytical
Used for calibration in analysis.
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Standard reference material
SRM 199 silica brick
NIST
Used for quality control during analysis.
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