研究目的
To develop a one-step fabricated multi-responsive walnut-like micromotor for autonomous movement, controlled motion, and oil removal in environmental applications.
研究成果
The walnut-like micromotor, fabricated via one-step electrospinning, exhibits autonomous motion in H2O2, light-controlled speed, magnetic-guided direction, and effective oil removal due to its hydrophobic and porous structure, showing promise for environmental remediation with potential for recycling via magnetic separation.
研究不足
The micromotor has moderate speed compared to others, may require optimization for higher velocity, and is limited to environments with H2O2 fuel; reusability is demonstrated but long-term stability and scalability for industrial applications are not fully addressed.
1:Experimental Design and Method Selection:
The study uses a one-step electrospinning method to fabricate micromotors from a blend of PCL, Fe3O4NPs, and catalase, leveraging phase separation for asymmetric structure.
2:Sample Selection and Data Sources:
Materials include catalase, Fe3O4NPs, PCL, and chemicals from Sigma Aldrich and J&K Scientific; samples are electrospun microstructures.
3:List of Experimental Equipment and Materials:
Equipment includes a syringe pump, high voltage power source, SEM (Carl Zeiss Supra 55), fluorescence microscope (Leica DM4000M), mercury lamp (Excelitas Technologies Model X-Cite 120Q), microscope (Nikon Eclipse 80i), spectrophotometer (PerkinElmer Lambda 750), infrared thermometer (Aladdin Company I5771-01), and contact angle system (Dataphysics OCA 20). Materials include PCL, Fe3O4NPs, catalase, H2O2, mineral oil, sodium cholate, dichloromethane, DMSO.
4:0). Materials include PCL, Fe3O4NPs, catalase, H2O2, mineral oil, sodium cholate, dichloromethane, DMSO. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: PCL is dissolved in dichloromethane, mixed with catalase and Fe3O4NPs, sonicated, electrospun at 18 kV with a 21-gauge needle, 10 cm distance, and 5 mL/h flow rate. Motion is initiated in H2O2 solution, observed under microscopy, and analyzed with PhysVis software. Oil removal experiments involve dispersing oil in water with sodium cholate and H2O
5:Data Analysis Methods:
Velocity is analyzed from videos using PhysVis software; transmittance is measured with UV-Vis spectroscopy; temperature is measured with an infrared thermometer; contact angle is measured with a contact angle system.
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scanning electron microscope
Supra 55
Carl Zeiss
Characterization of microstructure morphology and composition analysis with EDX
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fluorescence microscope
DM4000M
Leica
Observation of fluorescence from FITC-labeled catalase in micromotors
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mercury lamp
X-Cite 120Q
Excelitas Technologies
Light source for photothermal control of micromotor speed
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spectrophotometer
Lambda 750
PerkinElmer
UV-Vis spectral analysis for transmittance measurements
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microscope
Eclipse 80i
Nikon
Observation and recording of micromotor motion
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infrared thermometer
I5771-01
Aladdin Company
Non-contact temperature measurement around micromotors
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contact angle system
OCA 20
Dataphysics
Measurement of contact angle to assess hydrophobicity
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syringe pump
Pumping polymer solution during electrospinning
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high voltage power source
Application of voltage for electrospinning
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neodymium magnet
Application of external magnetic field for direction control
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